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掺铅TiO2薄膜的制备及光催化性能
引用本文:杨睿婷,李文军,王明文,方春英.掺铅TiO2薄膜的制备及光催化性能[J].北京科技大学学报,2005,27(4):462-464.
作者姓名:杨睿婷  李文军  王明文  方春英
作者单位:北京科技大学应用科学学院,北京,100083
摘    要:以钛酸四丁酯为前驱体,采用溶胶-凝胶法在玻璃板表面制得均匀的TiO2,并利用浸渍法镀pb2 得到掺铅的TiO2,用紫外漫反射、荧光光谱分析等手段对其进行了表征.研究结果表明,掺杂铅离子使TiO2的荧光峰明显增强,吸收带边发生红移,在紫外光区和可见光区的吸收明显增强.以紫外灯为光源,通过对甲基橙的光催化降解研究,发现掺铅TiO2薄膜的光催化活性明显大于掺Ag,Bi及纯TiO2薄膜,这是提高TiO2光催化活性的有效方法.

关 键 词:  二氧化钛薄膜  光催化  膜的制备  光催化性能  film  capability  photocatalytic  方法  光催化活性  薄膜  发现  光催化降解  甲基橙  光源  紫外灯  吸收带边  可见光  紫外光区  红移  发生  增强  荧光峰
收稿时间:2004-04-04
修稿时间:2004-06-17

Synthesis and photocatalytic capability of Pb-TiO2 film
YANG Ruiting,LI Wenjun,WANG Mingwen,FANG Chunying.Synthesis and photocatalytic capability of Pb-TiO2 film[J].Journal of University of Science and Technology Beijing,2005,27(4):462-464.
Authors:YANG Ruiting  LI Wenjun  WANG Mingwen  FANG Chunying
Abstract:A TiO2 catalyst doped by Pb2+ was prepared by the sol-gel method and characterized by DRS and FS. The experimental results showed that Pb2+ strengthened the TiO2 fluorescence apex, the absorbance band edge moved in the red direction, and the absorbance strengthened obviously both in the UV range and in the visible range. Compared with Ag-TiO2, Bi-TiO2 and TiO2 films, the Pb2+-doped TiO2 thin film has the highest photocatalytic activity by studying the degradation of methyl orange under UV-ray, which is an effective way to increase the photocatalytic activity.
Keywords:lead  TiO2 thin film  photocatalysis
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