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V-Ti-Fe中间合金的精炼工艺
引用本文:王斌,刘奎仁,高腾跃,何季麟. V-Ti-Fe中间合金的精炼工艺[J]. 东北大学学报(自然科学版), 2012, 33(5): 689-693. DOI: -
作者姓名:王斌  刘奎仁  高腾跃  何季麟
作者单位:1. 东北大学材料与冶金学院,辽宁沈阳,110819
2. 西北稀有金属材料研究院,宁夏石嘴山,753000
基金项目:国家高技术研究发展计划项目
摘    要:以金属热还原法制备的V-Ti-Fe中间合金为原料,采用喷吹造渣的方式对其进行精炼研究,实验考察了渣系组成和精炼温度对精炼效果的影响.结果表明:渣体中m(CaF2)/m(CaO)值为3.0,TiO2用量为总渣量的10%,用渣量为合金用量的35%,精炼温度为1 600℃时,精炼效果较好;精炼后合金中的Al质量分数由7.11%降到了2.61%,合金中的Si质量分数变化较小,仅由1.25%降到了0.97%.XRD和SEM分析表明,精炼后合金中没有出现氧化物相,精炼有效地去除了合金中的氧化物夹杂,降低了合金的成分偏析.

关 键 词:V-Ti-Fe中间合金  精炼  CaO-CaF2渣系  吹氩  氧化物夹杂  

Study on Refining Process of V-Ti-Fe Master Alloy
WANG Bin,LIU Kui-ren,GAO Teng-yue,HE Ji-lin. Study on Refining Process of V-Ti-Fe Master Alloy[J]. Journal of Northeastern University(Natural Science), 2012, 33(5): 689-693. DOI: -
Authors:WANG Bin  LIU Kui-ren  GAO Teng-yue  HE Ji-lin
Affiliation:1.School of Materials & Metallurgy,Northeastern University,Shenyang 110819,China;2.Northwest Rare Metal Materials Research Institute,Shizuishan 753000,China.)
Abstract:The spray refining process was carried out to reduce the impurities of V-Ti-Fe master alloy.The influences of slag compositions and temperature on refining effect were investigated.The results showed that when the ratio of m(CaF2)/m(CaO) is 3.0,the slag amount is 35% of the alloy amount,the TiO2 amount is 10% of the slag amount and the refining temperature is 1 600 ℃,a good refining effect is obtained.The content of Al decreases to 2.61% from 7.11% after the refining process.However the content of Si just decreases to 0.97% from 1.25%,the change range is smaller.XRD and SEM results showed that the refining process can remove oxide inclusions effectively.In addition,the componential segregation of the alloy is reduced after the refining process.
Keywords:V-Ti-Fe master alloy  refining  CaO-CaF2 slag system  argon blowing  oxide inclusion
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