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| 4,4'-联吡啶类超分子化合物的合成、晶体结构及表征 | |
| 引用本文： | 路璐,张宏伟,刘婷婷,袁菊,何林芯.4,4'-联吡啶类超分子化合物的合成、晶体结构及表征[J].四川理工学院学报(自然科学版),2013,26(2):15-19. |
| 作者姓名： | 路璐 张宏伟 刘婷婷 袁菊 何林芯 |
| 作者单位： | 1. 四川理工学院功能材料研究所,四川自贡643000;四川理工学院化学与制药工程学院,四川自贡643000 2. 四川理工学院化学与制药工程学院,四川自贡,643000 3. 四川理工学院功能材料研究所,四川自贡,643000 |
| 基金项目： | 四川理工学院基金项目，四川理工学院大学生创新基金项目 |
| 摘 要： | 采用水热合成法,利用4,4'-联吡啶为桥联配体得到两种新型超分子化合物(DPA)·0.5(4,4'-bipy)](1)和Cd(H2O)2·(4,4'-bipy)2]2DSTA(2)(DPA=2,2'-联苯二甲酸、DSTA=2,2'-二硫代水杨酸),并通过X-射线单晶衍射分析、X-射线粉末衍射分析、元素分析和红外光谱对产物进行了表征。研究表明,化合物1通过O-H…N和C-H…O氢键构筑成2D的网络结构,化合物2中心镉离子为六配位构成1个八面体的配位结构,同时,化合物2中包含一个16.112×17.535(4,4)的2D拓扑结构。 |
| 关 键 词： | 4 4'-联吡啶 晶体结构 水热合成 氢键 |
Syntheses, Properties and Crystal Structures of the Supramolecula Compound Formed by 4, 4'-bipyridine |
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| LU Lu , ZHANG Hong-wei , LIU Ting-ting , YUAN Ju , HE Lin-xin.Syntheses, Properties and Crystal Structures of the Supramolecula Compound Formed by 4, 4'-bipyridine[J].Journal of Sichuan University of Science & Engineering:Natural Science Editton,2013,26(2):15-19. | |
| Authors: | LU Lu ZHANG Hong-wei LIU Ting-ting YUAN Ju HE Lin-xin |
| Institution: | a(a.Institute of Functional Materials;b.School of Chemical and Pharmacentical Engineering,Sichuan University of Science & Engineering,Zigong 643000,China) |
| Abstract: | Two new compounds,(DPA)·0.5(4,4′-bipy)](1) and Cd(H2O)2·(4,4′-bipy)2]·2DSTA(2),have been synthesized with 4,4′-bipyridine been hydrothermally synthesized and structural characteristic is obtained by elemental analysis,X-ray diffraction,IR spectroscopy and single-crystal X-ray diffraction.The structure of the compound 1 exhibits two-dimensional networks through O-H…N and C-H…O bonds.In compound 2,the Cd(II) ion is six-coordinated with a regular octahedral coordination geometry.The research shows that this arrangement gives rise to a(4,4) connecting 2D topologic grid sheet with large rings of 16.112×17.535 in diagonal distances. |
| Keywords: | 4 4′-Bipy crystal structure hydrothermal synthesis Hydrogen bonding |
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