| 氯代芳烃的偶联反应在工业化中间体合成中的应用 |
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| 引用本文： | 李宝岩,汪余,刘凯泓,刘国华,金荣华.氯代芳烃的偶联反应在工业化中间体合成中的应用[J].上海师范大学学报(自然科学版),2020,49(4):433-442. |
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| 作者姓名： | 李宝岩 汪余 刘凯泓 刘国华 金荣华 |
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| 作者单位： | 上海师范大学化学与材料科学学院,上海200234;上海师范大学化学与材料科学学院,上海200234;上海师范大学化学与材料科学学院,上海200234;上海师范大学化学与材料科学学院,上海200234;上海师范大学化学与材料科学学院,上海200234 |
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| 基金项目： | 国家自然科学基金（21672149） |
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| 摘 要： | 近年来,氯代芳烃的偶联反应在天然产物、生物活性物质、医药、杀菌剂等中间体的合成中得到了广泛使用,这为它们的工业化生产提供了可能.简述了氯代芳烃的Suzuki偶联、Heck偶联和Sonogashira偶联反应在工业化中间体合成中的几个应用实例.
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| 关 键 词： | 氯代芳烃 Suzuki偶联 Heck偶联 Sonogashira偶联 工业化中间体 |
| 收稿时间： | 2019/11/19 0:00:00 |
Synthetic applications of coupling reactions with aryl chlorides in the industrial intermediates |
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| LI Baoyan,WANG Yu,LIU Kaihong,LIU Guohua and JIN Ronghua.Synthetic applications of coupling reactions with aryl chlorides in the industrial intermediates[J].Journal of Shanghai Normal University(Natural Sciences),2020,49(4):433-442. |
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| Authors: | LI Baoyan WANG Yu LIU Kaihong LIU Guohua and JIN Ronghua |
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| Institution: | College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China,College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China,College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China,College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China and College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China |
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| Abstract: | Recently, the coupling reactions of aryl chlorides have been widely used in the syntheses of intermediates for natural products, bioactive substances, pharmaceuticals, fungicides etc., which provides the possibility for their industrial production. This review summarizes some synthetic applications of coupling reactions with aryl chlorides, such as Suzuki coupling, Heck coupling, Sonogashira coupling reactions reported in the literatures. |
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| Keywords: | aryl chloride Suzuki coupling Heck coupling Sonogashira coupling industrial intermediate |
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