| [Co(2，3tri)(pz)Cl]2+体系配合物水解-重排机理研空 |
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| 引用本文： | 罗绪强,陶朱,张广义,祝黔江. [Co(2，3tri)(pz)Cl]2+体系配合物水解-重排机理研空[J]. 贵州大学学报(自然科学版), 2000, 17(2): 115-119 |
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| 作者姓名： | 罗绪强 陶朱 张广义 祝黔江 |
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| 作者单位： | 贵州大学应用化学研究所,贵阳,550025;贵州大学基础部,贵阳,550025 |
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| 摘 要： | 本文提出了一个「Ｃｏ（三元胺）（二元胺）Ｃｌ」＾２＋型的配合物及其异构体的重排机理模型,它包含了所有异构体间的转换关系,这一模型表面式异构体在重排过程中的重要性,利用对映异构体旋光性质及其可能的变化提出了可能存在一与经典模式不同的中间体假设。
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| 关 键 词： | [CoN5Cl]2+配合物 重排机理模型 中间体 |
| 文章编号： | 1000-5269(2000)02-0115-05 |
| 修稿时间： | 2000-04-10 |
The Complexes of[Co ( 2,3 -tri ) (pz) Cl] 2 + System Study on Rearrangement with a Special Intermediate |
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| Luo Xuqiang,Tao Zhu,Zhang Guangyi,ZHU Qianjiang. The Complexes of[Co ( 2,3 -tri ) (pz) Cl] 2 + System Study on Rearrangement with a Special Intermediate[J]. Journal of Guizhou University(Natural Science), 2000, 17(2): 115-119 |
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| Authors: | Luo Xuqiang Tao Zhu Zhang Guangyi ZHU Qianjiang |
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| Abstract: | A model showing the rearrangement of the [Co (triarnine) (diamine) C; ]2 +complexes with optical activity has been suggested. It covers the rearrangements between the fac - isomers, the fac - and met - isomer, also the mcr - isomers. This model reveals that the fac- isomers are particularly important for the detailed study of the stereochrnistry, and there could be a pivot other than the classical intermediates in the reactions. |
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| Keywords: | [CoN5Cl]2+complexes rearrangement courses optical activity intermediate |
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