Synthesis and magnetic property of a nitroxide based on C60 |
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| Authors: | SHI Zhiqiang LI Yuliang GE Zhongxin ZHU Daoben |
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| Abstract: | The compounds containing stable nitroxide radicals possess magnetic properties for the free radical have net magnetic moment. Oxidization of the [60]fulleropyrolidine obtained from the reaction of C60 with diketone and 2-aminoisobutyric acid by m-chloroperoxybenzoic acid gives a new nitroxide integrated with C60. The stable nitroxide based on C60 is confirmed to be antiferro- magnetism with quantum design superconducting quantum interference device (SQUID). |
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| Keywords: | ferromagnet fullerene nitroxide 1 3-dipolar circle addition reaction |
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