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用P538分离富集微量钪
引用本文:童珏,张列清.用P538分离富集微量钪[J].湘潭大学自然科学学报,1989,11(2):31-34.
作者姓名:童珏  张列清
作者单位:湘潭大学化学系 (童珏),湘潭大学化学系(张列清)
摘    要:探讨了P-538萃取钪的条件。和Th~(4 ),Ce~(4 )相似,P-538对钪有极好的萃取能力,即使在高酸下也近于完全萃取,因而可用于钪与其它元素(除Th~(4 )与Ce~(4 )外)的分离,萃合物的组成经测定为Sc(HA)_3。

关 键 词:P538    溶剂萃取

THE SEPARATION AND CONCENTRATION OF TRACE SCANDIUM BY P-538
Tong Jue Zhang Lieqing.THE SEPARATION AND CONCENTRATION OF TRACE SCANDIUM BY P-538[J].Natural Science Journal of Xiangtan University,1989,11(2):31-34.
Authors:Tong Jue Zhang Lieqing
Institution:Department of Chemistry
Abstract:P-538, monomyristyl phosphate, is a good extractant for scandium.The extraction is nearly complete even at the acidity is as high as8 mol/L HC1. This method may be used for separating and concentratingscandium from many coexisting elemens (rare earths, alkaline earths,uranium and iron) except tetravalent metals (Ce~(4 ), Th~(4 ) etc). The com-position of the extracted adduct was comfirmed as Sc(HA)_3 by experi-ments.
Keywords:Monomyristyl phosphate  P-538  Scandium  Solvent extraction  
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