| 氯丙基取代的杯芳烃衍生物的合成 |
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| 引用本文： | 朱建国,朱晓红,武家荣.氯丙基取代的杯芳烃衍生物的合成[J].河南科技大学学报(自然科学版),2006,27(1):92-95. |
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| 作者姓名： | 朱建国 朱晓红 武家荣 |
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| 作者单位： | 1. 连云港师范高等专科学校,化学系,江苏,连云港,222006
2. 海州高级中学,化学教研室,江苏,连云港,222023 |
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| 基金项目： | 江苏省教育厅科研基金项目(2002-J-251) |
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| 摘 要： | 以对叔丁基杯n]芳烃1a-1c(n=4,6,8)和间苯二酚杯芳烃1d-1e(R=C6H5,p-HOC6H4)为原料,在碳酸钾存在下以丙酮为溶剂与1-溴-3-氯丙烷反应,得到下缘为氯丙基取代的杯芳烃衍生物2a-2e。进一步以2b-2d为原料,在碳酸钾存在下以丙酮为溶剂与咔唑反应,得到丙基桥连的杯芳烃咔唑衍生物3a-3c。通过红外光谱,核磁共振氢谱等确定了上述产物的结构。
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| 关 键 词： | 杯芳烃 氯丙基 烃基化反应 取代 |
| 文章编号： | 1672-6871（2006）01-0092-04 |
| 收稿时间： | 2005-03-07 |
| 修稿时间： | 2005年3月7日 |
Synthesis of Three-methyl-chlorine-substituted Calixarenes Derivatives |
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| ZHU Jian-Guo,ZHU Xiao-Hong,WU Jia-Rong.Synthesis of Three-methyl-chlorine-substituted Calixarenes Derivatives[J].Journal of Henan University of Science & Technology:Natural Science,2006,27(1):92-95. |
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| Authors: | ZHU Jian-Guo ZHU Xiao-Hong WU Jia-Rong |
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| Institution: | ZHU Jian-Guo~1,ZHU Xiao-Hong~2,WU Jia-Rong~1 |
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| Abstract: | Tert-butylcalixarenes 1a-1c(n=4,6,8) or resorcinarenes 1d-1e(R=C_6H_5,p-HOC_6H_4) were alkylated by 1-bromine-3-chloropropane in refluxing acetone with anhydrous K_2CO_3 as solid base.To get and make cup aromatic hydrocarbon derivative 2a-2e that reason replaced for third base of chlorine.React with 2b-2d so as to acetone for the solvent and carbazole under potassium have in carbonic acid to step forward,get cup aromatic hydrocarbon carbazole derivative 3a-3c connected with in third base bridge.The structures of all new products were characterized by IR and 1HNMR spectroscopy. |
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| Keywords: | Calixarenes Three methyl chlorine Alkylation Replace |
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