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一种制备SiO2膜的方法——氧等离子体处理聚硅烷涂层
引用本文:谢茂浓,唐琳,彭志坚,傅鹤鉴.一种制备SiO2膜的方法——氧等离子体处理聚硅烷涂层[J].四川大学学报(自然科学版),2000,34(6):873-878.
作者姓名:谢茂浓  唐琳  彭志坚  傅鹤鉴
作者单位:1. 四川大学物理系,成都 610064
2. 四川大学化学系,成都610064
摘    要:作者利用低温氧等离子体处理聚硅烷涂层,成功地制备了SiO2膜.由IR谱给出的Si-O键的吸收峰波数,随氧等离子体处理时间的不同在1065~1088cm-1范围变化;XPS谱给出Si2p的结合能为103.3~103.5eV,硅氧原子比为1:1.99;激光椭园偏振仪测得折射率在1.30~1.55范围;MOS电容的高频C-V特性曲线表明,平带电压为正,计算得氧化物电荷的电性为负,密度为6.6×1010~8.8×1011cm-2,其大小可以通过改变处理条件进行控制;BT实验表明,可动电荷密度为(3~6)×1010cm-2,这种新型的SiO2膜可望在微电子器工艺中得到应用.

关 键 词:聚硅烷  氧等离子体处理  氧化物电荷  二氧化硅膜  硅半导体器件  电荷密度  结合能  制备

A METHOD OF MADE SiO2 THIN FILM --Polysilanes COAT WERRE TREATED WITH OXYGEN PLASMA
XIE Mao-nong,TANG Lin,PEBG Zhi-jian,FU He-jian.A METHOD OF MADE SiO2 THIN FILM --Polysilanes COAT WERRE TREATED WITH OXYGEN PLASMA[J].Journal of Sichuan University (Natural Science Edition),2000,34(6):873-878.
Authors:XIE Mao-nong  TANG Lin  PEBG Zhi-jian  FU He-jian
Abstract:A type of SiO2 thin films was successfully obtained in a condition of temperature less than 60℃ when polysilanec coat were treated with oxygen plasma. IR absorption peaks of these films are in 1065~1088cm-1, Si2p binding energy is in 103.3~103.5eV, Si:O=1:1.99. The refractive index of htese films are in the range of 1.30~1.55. The C-V curves of these films MOS capacitors indicated that their flatband voltage are positive, oxide charges are negative. Their densities are in the range of 6.6×1010~8.8×1011 .cm-2 by calculation and they can be controlled by the condition of oxygen plasma. Mobile charges are in (3~6)×1010cm-2 by treaument of rhe bias-temperature. The type of SiO2 films may find a promising application in microelectronic technology.
Keywords:polysilanes  treated with oxygen plasma  SiO2 thin film  oxide charges
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