| 从[MoS4]^2-制备一个[MoOS3]^2-型簇合物的低热固相反应机理 |
| |
| 引用本文： | 王荣,孙静静,金琼花.从[MoS4]^2-制备一个[MoOS3]^2-型簇合物的低热固相反应机理[J].首都师范大学学报(自然科学版),2009,30(6):20-23. |
| |
| 作者姓名： | 王荣 孙静静 金琼花 |
| |
| 作者单位： | 首都师范大学化学系,北京,100048 |
| |
| 摘 要： | 首次以含MoS4]^2-离子的（NH4）2MoS4为原料,与Cu（AC）2.H2O和PPh3在空气中研磨使其发生固相反应得到红色的固体.将此固体经CH3CN萃取,放置几天后可得到红黑色单晶MoCu3OS3（PPh3）3（CH3COO）].测试了其晶体结构,并对该低热固相反应的机理进行了研究.
|
| 关 键 词： | 固相合成 晶体结构 Mo-Cu-S簇合物 反应机理 |
The Mechanism of the Low-heating Soild State Reaction of synthesis one [MoOS3]2-type cluster by[MoS4]2- |
| |
| Wang Rong,Sun Jingjing,Jin Qionghua.The Mechanism of the Low-heating Soild State Reaction of synthesis one [MoOS3]2-type cluster by[MoS4]2-[J].Journal of Capital Normal University(Natural Science Edition),2009,30(6):20-23. |
| |
| Authors: | Wang Rong Sun Jingjing Jin Qionghua |
| |
| Institution: | (Department of Chemistry, Capital Normal Univefisty, Beijing 100048) |
| |
| Abstract: | The MoOS3] type of cluster MoCu3OS3（PPh3）3（CH3COO）] was first synthesized by the reaction of （NH4）2MoS4 containing MoS4] 2-ion,PPh3 and Cu（AC）2·H2O in the soild state,and the complex was characterized by IR,X-ray structure determination. The mechanism of this reaction is discussed. |
| |
| Keywords: | solid state synthesis crystal structure Mo-Cu-S cluster reaction mechanism |
| 本文献已被 维普 万方数据 等数据库收录！ |
