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| 以芳胺为端基的酰胺型开链冠醚及其配合物的合成与表征 | |
| 引用本文： | 秦宝锋,王耀宁,唐中华,焦天权,胡丽天.以芳胺为端基的酰胺型开链冠醚及其配合物的合成与表征[J].兰州大学学报(自然科学版),2006,42(1):86-88. |
| 作者姓名： | 秦宝锋 王耀宁 唐中华 焦天权 胡丽天 |
| 作者单位： | 1. 兰州大学化学化工学院,甘肃,兰州,730000;中国科学院兰州化学物理研究所,甘肃,兰州,730000 2. 兰州大学化学化工学院,甘肃,兰州,730000 3. 中国科学院兰州化学物理研究所,甘肃,兰州,730000 |
| 摘 要： | 以对硝基苯胺和对甲基苯胺二种芳胺为端基合成了6种酰胺型开链冠醚,通过IR,1HNMR及MS确定了它们的结构,同时用N,N'-二(对硝基苯胺)-3-氧杂戊二酰胺为配体与轻稀土硝酸盐进行了配位研究,合成了5种轻稀土硝酸盐配合物,通过元素分析和IR分析了其结构. |
| 关 键 词： | 对甲基苯胺 对硝基苯胺 酰胺型开链冠醚 |
| 文章编号： | 0455-2059（2006）01-0086-03 |
| 收稿时间： | 2004-10-09 |
| 修稿时间： | 2004-10-09 |
Synthesis and characterizaton of open chain crown ethers and their complexes with phenyl amines as the terminal group |
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| QIN Bao-feng,WANG Yao-ning,TANG Zhong-hua,JIAO Tian-quan,HU Li-tian.Synthesis and characterizaton of open chain crown ethers and their complexes with phenyl amines as the terminal group[J].Journal of Lanzhou University(Natural Science),2006,42(1):86-88. | |
| Authors: | QIN Bao-feng WANG Yao-ning TANG Zhong-hua JIAO Tian-quan HU Li-tian |
| Institution: | 1. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China; 2. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
| Abstract: | Six open crown ethers were synthesized for the first time by using p-toluidime and 4-nitroaniline as the terminal group. Through IR, ^1H NMR and MS, we have characterized their structures. And five new rare earth complexes with L2 as ligand were synthesized. Elemental analysis shows that they have different chemical formulas. Their chemical and physical properties were studied with conductance and IR. |
| Keywords: | open-chain crown ether p-toluidime 4-nitroaniline |
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