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Photocatalytic effect of nature and modified V-bearing rutile
作者姓名:LUAnhuai  GUOYanjun  LIUJuan  LIUFei  WANGChangqiu  LINing  LIQiaorong
作者单位:SchoolofEarthandSpaceSciences,PekingUniversity,Beijing100871,China
摘    要:A natural rutile TiO2, which displays photocatalysis on degrading halohydrocarbon pollutants, was reported. The rutile contains up to 1.22% V2O5 (weight percent). Substitutions of Ti by V, as well as Fe, Cu and Zn, result in lattice distortions and defects. Grinding, heating and quenching modify the surface characteristics of ruffle, and consequently increase its photoactivity. It is found that the heating and quenching treatments enhance visible-light absorption of ruffle, especially at 1000 and 1100℃. Ground rutile is effective to degrade tetrachloroethylene and trichloroethylene. While, heating at 1000℃, and quenching at 1000 and 1100℃ distinctly improve degradation rate of samples. The special properties of the natural rutile have particular capabilities in photocatalytic oxidation, especially in degradation of halohydrocarbons.

关 键 词:光催化作用  天然金红石  改性金红石  TiO2  卤代烃  降解  有机污染物
收稿时间:2004-04-01
修稿时间:2004-07-26

Photocatalytic effect of nature and modified V-bearing rutile
LUAnhuai GUOYanjun LIUJuan LIUFei WANGChangqiu LINing LIQiaorong.Photocatalytic effect of nature and modified V-bearing rutile[J].Chinese Science Bulletin,2004,49(21):2284-2287.
Authors:Anhuai  Lu  Yanjun  Guo  Juan  Liu  Fei  Liu  Changqiu  Wang  Ning  Li  Qiaorong  Li
Institution:(1) School of Earth and Space Sciences, Peking University, 100871 Beijing, China
Abstract:A natural rutile TiO2, which displays photocatalysis on degrading halohydrocarbon pollutants, was reported. The rutile contains up to 1.22% V2O5 (weight percent). Substitutions of Ti by V, as well as Fe, Cu and Zn, result in lattice distortions and defects. Grinding, heating and quenching modify the surface characteristics of rutile, and consequently increase its photoactivity. It is found that the heating and quenching treatments enhance visible-light absorption of rutile, especially at 1000 and 1100 °C. Ground rutile is effective to degrade tetrachloroethylene and trichloroethylene. While, heating at 1000 °C, and quenching at 1000 and 1100 °C distinctly improve degradation rate of samples. The special properties of the natural rutile have particular capabilities in photocatalytic oxidation, especially in degradation of halohydrocarbons.
Keywords:nature and modified V-bearing rutile  environmental properties  photocatalyst  halohydrocarbon  organic pollutant  deg- radation method  
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