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化合物Ce_3Rh_2Ga_2和Ce_3Rh_3Si_2的晶场效应计算
引用本文:薛绛琴,刘海瑞,路莹,李玉山,路庆凤.化合物Ce_3Rh_2Ga_2和Ce_3Rh_3Si_2的晶场效应计算[J].河南师范大学学报(自然科学版),2009,37(5).
作者姓名:薛绛琴  刘海瑞  路莹  李玉山  路庆凤
作者单位:1. 河南师范大学,物理与信息工程学院,河南,新乡,453007
2. 洛阳师范学院,物理系,河南,洛阳,471022
3. 山东菏泽学院,物理系,山东,菏泽,2740151
基金项目:河南省教育厅自然科学基金, 
摘    要:通过对D.Kaczorowski等人磁化率倒数—温度曲线的模拟,得到了稀土化合物Ce3Rh2Ga2和Ce3Rh3Si2的晶场系数、分裂能和相应波函数,计算结果与实验吻合较好.计算表明:Kramers离子Ce3+基态简并部分消除得到了双基态.

关 键 词:Ce3Rh3Ga2  Ce3Rh2Si2  磁化率  晶场效应

Investigation on Crystalline Electric Field Effect of Compound Ce3Rh2Ga2 and Ce3Rh3Si2
XUE Jiang-qin,LIU Hai-rui,LU Ying,LI Yu-shan,LU Qing-feng.Investigation on Crystalline Electric Field Effect of Compound Ce3Rh2Ga2 and Ce3Rh3Si2[J].Journal of Henan Normal University(Natural Science),2009,37(5).
Authors:XUE Jiang-qin  LIU Hai-rui  LU Ying  LI Yu-shan  LU Qing-feng
Abstract:The crystalline electric field(CEF) parameters,the CEF splitting levels and corresponding wave functions of compounds Ce3Rh2Ga2and Ce3Rh3Si2 are obtained by means of simulating the temperature dependence of inverse magnetic susceptibility measured by D.Kaczorowski group.The calculated results are in good agreement with the experimental data.The CEF analysis shows that Kramers ion Ce3+ has a doublet ground state.
Keywords:Ce3Rh3Ga2  Ce3Rh2Si2
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