硅氧基苯基卟啉的合成及表征 |
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引用本文: | 来国桥,;吕素芳,;李美江,;蒋剑雄,;沈永嘉,;邱化玉.硅氧基苯基卟啉的合成及表征[J].中国科技论文在线,2008(9):638-642. |
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作者姓名: | 来国桥 ;吕素芳 ;李美江 ;蒋剑雄 ;沈永嘉 ;邱化玉 |
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作者单位: | [1]杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州310012; [2]华东理工大学精细化工研究所,上海200237 |
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基金项目: | 国家自然科学基金资助项目(50475052); 高等学校博士学科点专项科研基金资助项目(20040145001); 教育部科学技术研究重大项目(104190); 泰山学者建设工程专项经费资助 |
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摘 要: | 本文首次将三甲基硅基、乙烯基二甲基硅基和二苯基甲基硅基接枝到四羟基苯基卟啉上,制得三种新型卟啉衍生物。采用质谱、核磁、元素分析和红外光谱表征了它们的结构并对它们的溶解性能进行研究。同时研究了不同取代基团卟啉、不同中心金属离子四羟基苯基卟啉的紫外-可见光谱,还进行了荧光光谱分析。
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关 键 词: | 有机化学 硅氧基苯基卟啉 改性 氯硅烷 |
Synthesis and characterization of siloxyphenyl porphyrins |
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Institution: | LAI Guoqiao,LV Sufang,LI Meijiang,JIANG Jianxiong,SHEN Yongjia,QIU Huayu (1. Key Lab of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012; 2. Laboratory of Advanced Materials and Institute of Fine Chemical, East China University of Science & Technology, Shanghai 200237) |
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Abstract: | In this paper, three new porphyrin derivatives are synthesized by modification of tetrahydroxylphenylporphyrin with chlorotrimethylsilane, chlorodimethylvinylsilane and chloro (methyl) diphenylsilane. The products were characterized by 1H-NMR, ESI-MS, elemental analysis and IR spectra. Solubility of products is investigated. The effects of different substitute group and central metal ion on UV-Vis spectra are studied and fluorescence spectra are studied. |
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Keywords: | organic chemistry siloxyphenyl porphyrin modified chlorosilane |
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