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气基预还原处理高铝铁矿石
引用本文:张作良,李强,李明明,邹宗树.气基预还原处理高铝铁矿石[J].东北大学学报(自然科学版),2013,34(4):556-559.
作者姓名:张作良  李强  李明明  邹宗树
作者单位:东北大学材料与冶金学院,辽宁沈阳,110819
基金项目:国家自然科学基金资助项目
摘    要:使用气基预还原的方法对一种全铁质量分数为3082%,Al2O3质量分数为2332%的高铝铁矿石进行铝铁分离研究.研究结果表明:1#球团于900℃、还原气氛为70%CO(体积分数)+30%H2、还原时间为77min时得到最高还原率7713%;2#球团于950℃、还原气氛为70%CO+30%H2、还原时间为80min时得到最高还原率822%;另外,2#球团在900℃以上还原时所能达到的最高还原率很接近;综合考虑,两种球团的最佳预还原温度为900℃;配加消石灰后,可以破坏原矿中铁、铝、硅之间的嵌布关系.X射线衍射分析结果表明,在还原过程中,出现了难还原的Fe2SiO4相和FeAl2O4相,这是导致还原难以进行的原因.

关 键 词:高铝铁矿石  气基预还原  还原率  铝铁分离  X射线衍射  

Treatment of High-Aluminium Content Iron Ore by Gas-Based Prereduction
Zhang,Zuo-Liang ,Li,Qiang ,Li,Ming-Ming ,Zou,Zong-Shu.Treatment of High-Aluminium Content Iron Ore by Gas-Based Prereduction[J].Journal of Northeastern University(Natural Science),2013,34(4):556-559.
Authors:Zhang  Zuo-Liang  Li  Qiang  Li  Ming-Ming  Zou  Zong-Shu
Institution:(1) School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China
Abstract:An approach of gas-based prereduction was introduced to treat a high-aluminium content iron ore with total iron of 30.82% (mass fraction) and Al2O3 of 23.32% for Al-Fe separation. The results showed that the maximum reduction rate of 1# pellets reached 77.13% by reduction for 77 minutes in the reduction atmosphere of 70%CO and 30%H2 in volume fraction at 900 °C. The maximum reduction rate of 2# pellets reached 82.2% by reduction for 80 minutes with 70%CO and 30%H2 in volume fraction at 950 °C. The maximum reduction rates achieved for 2# pellets at the temperatures above 900 °C were very close, so the optimal prereduction temperature of two kinds of pellets was 900 °C by taking all the factors into consideration. The additive of slaked lime undermined the existential relationship among ferreous, aluminiferous and silaceous minerals. X-ray diffraction results indicated that the phases Fe2SiO4 and FeAl2O4 which were difficult to deoxidize appeared in the process of reduction and made the reduction process difficult to carry on.
Keywords:High aluminum content iron ore  gas based prereduction  reduction rate  Al Fe separation  X ray diffraction  
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