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高导电H3PMo12O40掺杂聚苯胺微米棒的合成与表征
引用本文:王凤春,高凤梅,龚剑,刘艳波,瞿伦玉. 高导电H3PMo12O40掺杂聚苯胺微米棒的合成与表征[J]. 东北师大学报(自然科学版), 2005, 37(3): 41-44
作者姓名:王凤春  高凤梅  龚剑  刘艳波  瞿伦玉
作者单位:东北师范大学化学学院,吉林,长春,130024;通化师范学院化学系,吉林,通化,134000;东北师范大学化学学院,吉林,长春,130024;白城师范学院化学系,吉林,白城,137000
基金项目:教育部留学回国人员科研启动基金,吉林省自然科学基金
摘    要:分别以静电纺丝法制备的H3PMo12O40/ PVA和纯H3PMo12O40微米管为模板,制备了H3PMo12O40掺杂的聚苯胺微米棒材料,并运用红外光谱、X射线粉末衍射和扫描电镜进行了表征.四探针法测定了产品的电导率.结果表明:聚苯胺微米棒的直径在400 nm左右;最高电导率为3.3 S/ cm.

关 键 词:模板  聚苯胺微米棒  杂多酸  电导率
文章编号:1000-1832(2005)03-0041-04
收稿时间:2005-04-06
修稿时间:2005-04-06

Synthesis and characterization of high conducting PAn doped with H3PMo12O40
WANG Feng-chun,GAO Feng-mei,GONG Jian,LIU Yan-bo,QU Lun-yu. Synthesis and characterization of high conducting PAn doped with H3PMo12O40[J]. Journal of Northeast Normal University (Natural Science Edition), 2005, 37(3): 41-44
Authors:WANG Feng-chun  GAO Feng-mei  GONG Jian  LIU Yan-bo  QU Lun-yu
Abstract:H3PMo12O40/PVA and pure H3PMo12O40 microtubes template method synthesized PAn microrods doped with H3PMo12O40, respectively. The PAn microrods were characterized by IR, XRD spectra and SEM photographs. The conductivity of the materials was investigated by a standard four - point probe method. All results showed that the average diameter of the PAn mlcrorods was 400 nm and the highest conductivity of the PAn microrods was 3.3 S/cm.
Keywords:template   PAn microrods   heteropoly   conductivity
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