| 苯酚和甲醇气相邻位烷基化反应催化剂的研究进展 |
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| 引用本文： | 王艳力,张文祥,朱小梅,郑艳春,贾明君,蒋大振.苯酚和甲醇气相邻位烷基化反应催化剂的研究进展[J].黑龙江大学自然科学学报,2006,23(2):150-155. |
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| 作者姓名： | 王艳力 张文祥 朱小梅 郑艳春 贾明君 蒋大振 |
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| 作者单位： | 1. 吉林大学,化学学院,吉林,长春,130021
2. 长春泰尔茂医用器具有限公司,吉林,长春,130012 |
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| 基金项目： | 国家自然科学基金资助项目(20403006)，吉林省科技发展计划资助项目(20040563) |
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| 摘 要： | 综述了近年来苯酚和甲醇气相邻位烷基化反应方面的研究进展,着重分析了用于该反应的各类催化剂体系的研究状况,探讨了催化剂的酸碱中心性质和反应性能的关系、苯酚和甲醇烷基化的反应机理以及催化剂的失活原因等问题,并对今后的研究方向进行了展望。
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| 关 键 词： | 甲醇 苯酚 邻位烷基化 催化剂 进展 |
| 文章编号： | 1001-7011(2006)02-0150-06 |
| 修稿时间： | 2005年12月13 |
Advances in the catalysts for the vapour phase ortho-selective alkylation of phenol with methanol |
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| WANG Yan-li,ZHANG Wen-xiang,ZHU Xiao-mei,ZHENG Yan-chun,JIA Ming-jun,JIANG Da-zhen.Advances in the catalysts for the vapour phase ortho-selective alkylation of phenol with methanol[J].Journal of Natural Science of Heilongjiang University,2006,23(2):150-155. |
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| Authors: | WANG Yan-li ZHANG Wen-xiang ZHU Xiao-mei ZHENG Yan-chun JIA Ming-jun JIANG Da-zhen |
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| Abstract: | The recent progress in the catalysts for the vapour phase ortho-selective alkylation of phenol with methanol was summarized.The status of different catalysts was particularly introduced.Further more,various questions,such as the correlation between the acidic-basic properties of the catalysts and catalytic properties,reaction mechanism and the reason for deactivation,were discussed in detail.At last,the research direction we should strive in the future was forecasted. |
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| Keywords: | methanol phenol ortho-selective alkylation catalyst advance |
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