| 碳正离子1,2-氢或甲基迁移重排机理 |
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| 引用本文： | 王兰芳,吴英绵,卢金铭.碳正离子1,2-氢或甲基迁移重排机理[J].河北师范大学学报(自然科学版),1999(3). |
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| 作者姓名： | 王兰芳 吴英绵 卢金铭 |
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| 作者单位： | 河北师范大学化学系!河北石家庄050091(王兰芳)，石家庄大学化学系!河北石家庄050081(吴英绵)，河北省城建职工中专!河北保定071051(卢金铭) |
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| 摘 要： | 用量子化学计算研究了碳正离子 １，２ 重排的氢、甲基迁移重排机理，结果表明其历程是一种正离子系统中的原子迁移的协同历程，从而说明了一般有机理论中认为其历程为负离子型的迁移的观点是不确切的
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| 关 键 词： | MNDO 重排反应 历程 |
The Rearrangement Mechanism of 1,2 Hydrogen or Methyl in Carbenium lons |
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| WANG Lan fang ,WU Ying mian ,LU Jin ming.The Rearrangement Mechanism of 1,2 Hydrogen or Methyl in Carbenium lons[J].Journal of Hebei Normal University,1999(3). |
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| Authors: | WANG Lan fang WU Ying mian LU Jin ming |
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| Institution: | WANG Lan fang 1,WU Ying mian 2,LU Jin ming 3 |
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| Abstract: | The rearrangement mechanism of 1.2 hydrogen or methyl in carbenium ions was studied by quantum chemical calculation.The calculated results showed that the mechanism was concerted reaction of the atom migration in carbenium ions.Hence,the point of view was on exact that the mechanism of anion migration is considered in ordinary organic theory. |
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| Keywords: | MNDO rearrangement reaction mechanism |
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