Synthesis of a symmetrical tetrasubstituted cucurbit[6]uril and its host-guest inclusion complex with 2,2′-bipyridine |
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作者姓名: | DAY Anthony I |
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作者单位: | Chemistry Discipline,School of Physical Environmental and Mathe-matical Sciences,University College UNSW,Australian Defence Force Academy,Canberra ACT,Australia |
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摘 要: | Since the structure of the first cucurbituril, a cyclic oligomer of 6 units of glycoluril linked by 12 methylene bridges was determined by Freeman et al. in 19811,2], considerable interest has emerged inspired by this new receptor. The receptor properties have been examined in a variety of ways such as polyrotaxanes, molecular neck-laces, rotaxane dendrimers, cyclo-addition reactions which occur more rapidly inside the cavity, and the treatment of effluent from the dye industry2—12]. Almost…
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