| 杯芳烃衍生物分离介质的合成与表征 |
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| 引用本文： | 李莹,苏立强,王远.杯芳烃衍生物分离介质的合成与表征[J].齐齐哈尔大学学报(自然科学版),2009,25(1). |
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| 作者姓名： | 李莹 苏立强 王远 |
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| 作者单位： | 齐齐哈尔大学,化学与化学工程学院,黑龙江,齐齐哈尔,161006 |
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| 摘 要： | 提出了以自制的杯芳烃与甲基丙烯酰氯为原料合成杯芳烃衍生物,以杯芳烃衍生物和丙烯酰胺作为复合功能单体,将其运用到分子印迹技术中,制备的印迹聚合物分离介质,对模板分子苯甲酰胺及其结构类似物的分离效果,好于使用单一单体的效果, 当杯芳烃衍生物与丙烯酰胺的比例为1﹕3时,分离因子可达13.37.
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| 关 键 词： | 分子印迹技术 功能单体 杯芳烃衍生物 丙烯酰胺 |
The synthesis and characterization of calyx arene derivative as separation medium |
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| LI Ying,SU Li-qiang,WANG Yuan.The synthesis and characterization of calyx arene derivative as separation medium[J].Journal of Qiqihar University(Natural Science Edition),2009,25(1). |
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| Authors: | LI Ying SU Li-qiang WANG Yuan |
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| Institution: | College of Chemistry and Chemical Engineering;Qiqihar Uiniversity;Heilongjiang Qiqihar 161006;China |
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| Abstract: | It was reported that the calyx arene derivative was synthesized with calyx arene and methacryloyl chloride as raw materials.Using calyx arene derivative and acrylamide(AM) as the bi-funtional monomers,a molecularly imprinted polymer was prepared.The results of experiments indicate that the selectivity of the MIP,which is synthesized with a single functional monomer(calix arene derivative or acrylamide),is poor;while the selectivety of another MIP,which is synthesized with two functional monomers(calyx arene... |
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| Keywords: | molecularly imprinted technique functional monomers calix arene derivative acrylamide |
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