The free radical oxidation of the tetrahydrocannabinols |
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| Authors: | I. J. Miller N. K. McCallum C. M. Kirk B. M. Peake |
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| Affiliation: | (1) Chemistry Division, Department of Scientific and Industrial Research, Private Bag, Petone, (New Zealand);(2) Chemistry Department, University of Otago, Dunedin, (New Zealand) |
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| Abstract: | Summary The free radical oxidation of  1 and 6-tetrahydrocannabinol has been examined by spin trapping techniques and intermediates that would lead to cannabinol have been trapped. The 1st step in the oxidation of 1-THC involves the removal of 3-H, while for 6-THC, either 2-H or 5-H. Intermediates were isolated which could be pyrolysed to the diene and cannabinol. |
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