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Ca,Cu的含量对Bi(Sb)系材料相转变及超导电性的影响
引用本文:刘建,胡玉才.Ca,Cu的含量对Bi(Sb)系材料相转变及超导电性的影响[J].内蒙古大学学报(自然科学版),1995,26(6):696-700.
作者姓名:刘建  胡玉才
作者单位:内蒙古大学物理学系,大连水产学院
基金项目:内蒙古大学青年科学基金
摘    要:采用空气中固态反应的方法,制备了一系列Ca、Cu的含量不同的Bi(Sb)系超导材料。对这些样品进行了超导了性能测量,X射线衍射分析以及扫描电镜的形貌观察,系统地研究了Bi(Sb)系中Ca、Cu的含量对材料的相转变及超导性能的影响,发现各义组分中适量的Ca、Cu的超比例可以促进2212相向2223相的转变。

关 键 词:超导体  铋系  相转变  超导电性    

The Effect of the Amount of Ca and Cu on Phase Transition and Superconducting Properities in the Bi(Sb) System
Liu Jian Bai Peiguang Hu Yucai.The Effect of the Amount of Ca and Cu on Phase Transition and Superconducting Properities in the Bi(Sb) System[J].Acta Scientiarum Naturalium Universitatis Neimongol,1995,26(6):696-700.
Authors:Liu Jian Bai Peiguang Hu Yucai
Institution:Liu Jian1 Bai Peiguang1 Hu Yucai2
Abstract:y solid state reaction in air ,a series of Bi(Sb) system samples Bi_1.9Sb_0.1Sr_2Ca_nCu_(n 1)O_y areprepared ,in which the amount of Ca and Cu are different. We systematically investigated the ef-fect of Ca and Cu on Bi(Sb)system material phase transition and superconducting properities byXRD,SEM and superconductivity measurement.We found that just the right addition of Ca andCu in initial composition can accelerate phase transition from 2212 to 2223. The surplus part of Caand Cu in the sample formed Ca_2CuO_3.Adding too much of Ca and Cu will destroy the sample 'ssuperconducting properities.
Keywords:superconductivity Bi(Sb) system Ca_2CuO_3
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