| 以PS-P2VP嵌段共聚物为模板获得金-氧化铁复合纳米粒子有序排列 |
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| 引用本文： | 刘军,李学.以PS-P2VP嵌段共聚物为模板获得金-氧化铁复合纳米粒子有序排列[J].济南大学学报(自然科学版),2012(3):251-254. |
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| 作者姓名： | 刘军 李学 |
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| 作者单位： | 济南大学化学化工学院 |
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| 基金项目： | 国家自然科学基金(51173069);山东省自然科学基金(ZR2010BM009) |
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| 摘 要： | 采用具有两亲性的嵌段共聚物聚苯乙烯-b-聚二乙烯基吡啶嵌段物(PS-P2VP),与无机前躯体FeCl3和HAuCl4.xH2O在选择性溶剂甲苯中自组装,得到以P2VP/FeCl3/HAuCl4为核、PS为壳的球形胶束;硅片上的胶束经磞氢化钠水溶液还原后用紫外灯降解除去PS-P2VP后得到复合粒子。经场发射扫描电镜、扫描探针显微镜、X射线光电子能谱分析仪等表征及检测,结果表明:在2.2 keV和6.4 keV处分别检测出金和铁元素的信号峰,得到有序排列的金-氧化铁复合纳米粒子。
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| 关 键 词： | PS-P2VP 有序 复合纳米粒子 |
Preparation of Orderly Gold-Iron Oxide Nanoparticles Using Polystyrene-b-Polyvinyl Pyridine As Templates |
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| LIU Jun,LI Xue.Preparation of Orderly Gold-Iron Oxide Nanoparticles Using Polystyrene-b-Polyvinyl Pyridine As Templates[J].Journal of Jinan University(Science & Technology),2012(3):251-254. |
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| Authors: | LIU Jun LI Xue |
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| Institution: | (School of Chemistry and Chemical Engineering,University of Jinan,Jinan 250022,China) |
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| Abstract: | Amphiphilic block copolymer PS-P2VP,inorganic FeCl3 and HAuCl4·xH2O can self-assemble into composite micelles composed of a P2VP/FeCl3/HAuCl4 core and a PS shell in selective solvent toluene.Composite particles were produced by using NaBH4 solution to reduce and UV light degradation to remove PS-P2VP block copolymer.The obtained nanoparticles were characterized by field emission scanning electron microscopy(FESEM),atomic force microscope(AFM),and energy dispersive spectrometer(EDS).Experimental results show that signal peaks of gold and iron are detected at 2.2 keV and 6.4 keV,and a array of composite particles of gold-iron oxide are obtained. |
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| Keywords: | PS-P2VP order composite nanoparticle |
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