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钼无机-有机杂化材料的水热合成及表征
引用本文:魏波,曹慧群,林燕翠,吴冰. 钼无机-有机杂化材料的水热合成及表征[J]. 中国西部科技, 2009, 8(6): 6-7
作者姓名:魏波  曹慧群  林燕翠  吴冰
作者单位:深圳大学化学与化工学院,广东,深圳,518060
摘    要:
以钼酸钠为钼源,乙二胺为有机配体通过水热法合成了一种几何外形为长方体的紫红色晶体(C2H8N2)11[Na2Mo10P6O60],并利用XRD、SEM和DSC等分析测试手段对晶体的结构、形貌和性能进行了表征。实验表明最佳原料配比(摩尔比)为钼酸钠:磷酸:乙二胺:水=(0.41~1.00):(1.65~5.51):(0.063—4.07):111。

关 键 词:杂化材料    水热合成

Synthesis and Characterazation of Molybdenum Inorganic-organic Hybrids
WEI Bo,CAO Hui-qun,LIN Yan-cui,WU Bing. Synthesis and Characterazation of Molybdenum Inorganic-organic Hybrids[J]. Science and Technology of West China, 2009, 8(6): 6-7
Authors:WEI Bo  CAO Hui-qun  LIN Yan-cui  WU Bing
Affiliation:(School of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, P. R. China)
Abstract:
Molybdenum inorganic-organic hybrids (C2H8N2)11[Na2Mo10P6O60] were synthesized using sodium molybdate as the inorganic main body, the ethylene diamine as organic legend in hydrothermal system. The structure and properties were characterized by XRD, SEM and DSC techniques. The optimum ratio of raw material is nNaMo4.2H2O: nH3PO4: nEn: nH2O= (0.41-1.00) : (1.65-3.31) : (0.063-4.07) : 111.
Keywords:inorganic-organic hybrid materials  molybdenum  hydrothermal synthesis
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