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天然高岭土对Pb~(2+),Cd~(2+),Ni~(2+),Cu~(2+)的吸附及解吸性能研究
引用本文:蒋明琴,金晓英,王清萍,陈祖亮. 天然高岭土对Pb~(2+),Cd~(2+),Ni~(2+),Cu~(2+)的吸附及解吸性能研究[J]. 福建师范大学学报(自然科学版), 2009, 25(2)
作者姓名:蒋明琴  金晓英  王清萍  陈祖亮
作者单位:福建师范大学化学与材料学院,福建,福州,350108
基金项目:福建师范大学闽江学者人才引进基金,福建省青年人才基金 
摘    要:
探讨了吸附时间、溶液pH、重金属离子初始质量浓度、离子强度以及竞争吸附等因素对天然高岭土吸附水中Pb2+,Cd2+,Ni2+,Cu2+等重金属离子的影响.结果表明,pH、初始质量浓度、离子强度以及共存离子,是影响高岭土吸附重金属离子的主要因素;高岭土对Pb2+的吸附性能明显优于其它3种重金属离子,顺序为:Pb2+>Cd2+>Ni2+>Cu2+;吸附等温线均符合Freundlich型等温方程,说明高岭土对这几种离子都是典型的单分子层吸附;Pb2+,Cd2+,Ni2+,Cu2+离子解吸量大小顺序为:Pb2+<Ni2+<Cu2+<Cd2+.

关 键 词:高岭土  吸附  重金属离子  解吸

Study on Adsorption and Desorption of Pb~(2+),Cd~(2+),Ni~(2+) and Cu~(2+) by Natural Kaolin
JIANG Ming-qin,JIN Xiao-ying,WANG Qing-ping,CHEN Zu-liang. Study on Adsorption and Desorption of Pb~(2+),Cd~(2+),Ni~(2+) and Cu~(2+) by Natural Kaolin[J]. Journal of Fujian Teachers University(Natural Science), 2009, 25(2)
Authors:JIANG Ming-qin  JIN Xiao-ying  WANG Qing-ping  CHEN Zu-liang
Affiliation:College of Chemistry and Materials Science;Fujian Normal University;Fuzhou 350108;China
Abstract:
The effects of contact time,pH in solution,initial metal concentration,ionic strength and competition among the ions on adsorption of Pb2+,Cd2+,Ni2+ and Cu2+ by kaolin were discussed.The results showed that the ions adsorbed by kaolin were primarily affected by pH,initial concentration,ionic strength and the coexistence of ions.Pb2+ was adsorbed easiest than the others which followed the order: Pb2+> Cd2+> Ni2+> Cu2+.The adsorption isotherms of all four heavy metal ions accorded with the model of Freundlich...
Keywords:kaolin  adsorption  heavy metal ions  desorption  
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