Synthesis and Crystal Structure of New Supramolecular Adducts of[PtCl_6]~(2-) with Cucurbit [7] uril:[(H_3O)_2 [PtCl_6]_3 [C_(42)H_(42)N_(28)O_ (14)_2·H_2O |
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引用本文: | Yan Kun,Huang Zi-xiang,Liu Si-min,Liang Feng,Wu Cheng-tai . College of Chemistry and Molecular Sciences,Wuhan University,Wuhan ,Hubei,China, . Fujian Institute of Research on the Structure of Matter,CAS,Fuzhou ,Fujian,China.Synthesis and Crystal Structure of New Supramolecular Adducts of[PtCl_6]~(2-) with Cucurbit [7] uril:[(H_3O)_2 [PtCl_6]_3 [C_(42)H_(42)N_(28)O_ (14)_2·H_2O[J].武汉大学学报:自然科学英文版,2004(1). |
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作者姓名: | Yan Kun Huang Zi-xiang Liu Si-min Liang Feng Wu Cheng-tai . College of Chemistry and Molecular Sciences Wuhan University Wuhan Hubei China . Fujian Institute of Research on the Structure of Matter CAS Fuzhou Fujian China |
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作者单位: | Yan Kun1,Huang Zi-xiang2,Liu Si-min1,Liang Feng1,Wu Cheng-tai 1 1. College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,Hubei,China; 2. Fujian Institute of Research on the Structure of Matter,CAS,Fuzhou 350002,Fujian,China |
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基金项目: | SupportedbytheNationalNaturalScienceFoundationofChina (2 0 1 72 0 4 0 ) |
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摘 要: | 0 IntroductionCucurbit n]urils (Qn ,Fig .1.)arecyclicoligomersofnunitsofglycolurillinkedby 2nmethylenebridgesderivedfromformaldehyde.Theypossessacharacteristicannularshape,withtwoidenticalcarbonyl fringedportals1 ,2 ] .Themostcom moncucurbituril,Q6 ,wasreportedtoaccommodatedifferentguestssuchaswater3] ,THF4 6] ,xenon7] ,pyridium8] andp xylyenediammonium3] ionsandsoon .ThealkyldiaminesthreadthroughtheQ6 ,andformtherotaxanestructures9 1 3] .Metalions1 ,3 6 ,1 4 ,1 5] andclusters8,…
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