| 碳纳米管负载Mo-Co-S催化剂的能谱研究 |
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| 引用本文： | 董昆明,杨森林,崔玉民.碳纳米管负载Mo-Co-S催化剂的能谱研究[J].阜阳师范学院学报(自然科学版),2007,24(1):26-28. |
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| 作者姓名： | 董昆明 杨森林 崔玉民 |
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| 作者单位： | 阜阳师范学院,化学系,安徽,阜阳,236041 |
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| 基金项目： | 安徽省自然科学基金资助项目(050450301,070416240) |
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| 摘 要： | 碳纳米管负载的Mo-Co-S加氢脱硫催化剂,其对噻吩的HDS在一定的反应条件下显示出比常规载体γ-Al2O3或SiO2负载催化剂更高的催化活性;从能谱(XPS)表征的角度研究探讨了该类催化剂反应活性高的原因,并结合H2-TPR,H2-TPD等谱学表征的结果,讨论了CNTs载体的促进作用本质.
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| 关 键 词： | HDS Mo-Co-S 碳纳米管 XPS |
| 文章编号： | 1004-4329（2007）01-0026-03 |
| 收稿时间： | 2006-12-09 |
| 修稿时间： | 2006年12月9日 |
XPS Study of Mo-Co-S Catalyst Supported by Multi-walled Carbon Nanotubes |
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| DONG Kun-ming,YANG Sen-lin,CUI Yu-min.XPS Study of Mo-Co-S Catalyst Supported by Multi-walled Carbon Nanotubes[J].Journal of Fuyang Teachers College:Natural Science,2007,24(1):26-28. |
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| Authors: | DONG Kun-ming YANG Sen-lin CUI Yu-min |
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| Institution: | Department of Chemistry; Fuyang Teachers College; Fuyang Anhui 236041; China |
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| Abstract: | With a type of home-made multi-walled carbon nanotubes(CNTs) as support,CNT-supported Mo-Co-S catalysts,symbolized as x%(mass percentage)MoiCoj/CNT,were prepared by an incipient wetness technique.It was experimentally found that using the CNTs in place of γ-Al2O3 or SiO2 as support of the catalyst led to a significant increase in concentration of catalytically active Mo-species(Mo(4+)) at the surface of the functioning catalyst.This unique feature would be beneficial to generating microenvironments with higher Mo(4+) concentration of these kind of catalysts on the surface of the functioning catalyst,and thus be favorable to increasing the rate of the thiophene HDS reaction. |
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| Keywords: | XPS multi-walled carbon nanotubes CNT-supported Mo-Co-S catalyst thiophene HDS |
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