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矿物材料对核素Sr、Cs的吸附及其固化材料的性能研究
引用本文:易发成,李玉香,石正坤,康厚军. 矿物材料对核素Sr、Cs的吸附及其固化材料的性能研究[J]. 西南科技大学学报, 2006, 21(4): 1-7
作者姓名:易发成  李玉香  石正坤  康厚军
作者单位:1. 西南科技大学非金属矿研究所,四川绵阳,621010
2. 中国工程物理研究院二所,四川绵阳,621920
基金项目:国家自然科学基金资助项目(10376028)
摘    要:在分析若干矿物材料的基本物性基础上,对其吸附放射性核素锶、铯的性能进行了研究.沸石、钠化改性凹凸棒石粘土矿物对锶、铯具有优良的吸附性能.矿物对锶、铯的吸附以化学吸附为主,物理吸附不是决定的因素.由热活化高岭土、新疆沸石、改性凹凸棒粘土为基质材料构成的富铝碱矿渣粘土矿物胶凝材料具有高强、较低孔隙率、较少的有害孔、抗硫酸盐侵蚀和耐辐照性能好的特点.以此材料为基材的模拟放射性废物固化体Sr2 、Cs 的浸出率较低.

关 键 词:矿物材料      吸附  固化材料
文章编号:1671-8755(2006)04-0001-07
修稿时间:2006-10-08

Study on the Adsorptive Capabilities of Mineral Materials and Properties of Solidifying Materials for Radionuclide Sr, Cs
YI Fa-cheng,LI Yu-xiang,SHI Zheng-kun,KANG Hou-jun. Study on the Adsorptive Capabilities of Mineral Materials and Properties of Solidifying Materials for Radionuclide Sr, Cs[J]. Journal of Southwest University of Science and Technology, 2006, 21(4): 1-7
Authors:YI Fa-cheng  LI Yu-xiang  SHI Zheng-kun  KANG Hou-jun
Abstract:The adsorptive capabilities of mineral materials for radionuclide Sr,Cs were investigated on the ground of basic physics and chemical properties.Mineral materials with excellent adsorptive capabilities are zeolite and Na-plygorskite clay,and their adsorptions mainly belong to chemical adsorptions.The composition and some properties of Alumina-rich alkali-activated slag clay minerals(RA-AASCM)cementitious materials for immobilization of radioactive waste are studied.Experimental results show that heat activated kaolinite,Xinjiang zeolite,modified attapulgite clay are better constituents of RA-AASCM.RA-AASCM pastes exhibit high strength,low porosity,fewer harmful pores,high resistance to sulphate corrosion and to gamma irradiation.The Sr~(2 ),Cs~ leaching portion,of the simulated radioactive waste forms based on RA-AASCM,is low.
Keywords:mineral materials  Sr  Cs  adsorption  solidifying materials
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