Zr-xNb-4Sn alloys with low Young’s modulus and magnetic susceptibility for biomedical implants

The microstructure, mechanical and magnetic properties of Zr–x (8, 9, 10, wt.%)Nb–4Sn alloys were investigated to obtain novel Zr-based alloy with low Young’s modulus and magnetic susceptibility for biomedical implants. After homogenization annealing, hot forging and solution annealing, Zr–8Nb–4Sn, Zr–9Nb–4Sn and Zr–10Nb–4Sn alloys were composed of β+α″ phase, β+α″ phase, β+ω phase, respectively. The temperature at which the α" and ω phase were transformed into β phase during the heating process was about 200 ​°C, and the phase transformation temperature decreased with the increase of Nb element. Among all the Zr–x (x ​= ​8,9,10)Nb–4Sn(wt.%) alloys, Zr–9Nb–4Sn alloy had the lowest Young's modulus of 46.6 ​GPa and the low magnetic susceptibility of 1.294 ​× ​10⁻⁶ cm³g⁻¹, which has a good application prospect for biomedical applications.     

Computational diffusion kinetics and its applications in study and design of rare metallic materials

Computational diffusion kinetics(CDK),with a spirit of and being coupled with the computational thermodynamics(CT,or called as the CALPHAD technique),plays increasingly important role in the alloy design/optimization and microstructure control during the processing of advanced metallic materials.This paper is to highlight recent progress of CDK in research with great focus on novel Ti and Zr alloys,which was largely performed in the authors’group.It ends with one representative example of the applications of CDK,coupled with CT,quantitative phase field,and three-dimensional(3D)statistical calculation,in designing the heattreatment schedule for the dual phase(αβ)Ti–6Al–4V alloys.     

4,4-二硝基丁酸乙酯的合成研究

以丙烯酸乙酯与二硝基甲烷钾盐为反应原料,四丁基溴化铵为相转移催化剂,通过Michael加成反应合成4,4-二硝基丁酸乙酯。采用红外光谱、紫外可见光谱、质谱、核磁共振氢谱及元素分析等对产物结构进行了表征。通过单因素变量法探讨了反应时间、反应物料比、催化剂用量及反应温度对产物产率的影响,得出该反应最佳工艺条件：反应时间为60 min,反应温度为20℃,n丙烯酸乙酯：n二硝基甲烷钾盐为2：1,相转移催化剂四丁基溴化铵质量为二硝基甲烷钾盐质量的30%时,产物偕二硝基丁酸乙酯收率可达到33%。     

改进的区域解相算法及其在三维重建中的应用

解相位算法是位相三维轮廓测量技术的关键,基于区域的解相位算法是应用较为广泛的解相算法之一。但在实践中发现基于区域的解相算法存在一定问题:当被测物体表面存在阶跃形变结构或噪声较大时可能产生解相错误。通过对该算法解相过程的分析确定了错误产生的原因,并针对存在问题提出一种改进算法,在区域分割的基础上计算每点相位可靠度质量图,并根据计算的二阶差分质量图制定新的区域分割与合并策略对相位进行解算。实验结果表明,本文算法可显著提高基于区域解相算法的解相精度,对表面高度变化较为复杂、噪声较大的相位数据可进行有效处理,具有良好的重建精度和鲁棒性。     

全相位算法在相控阵天线幅相校正测量中的应用

相控阵天线波束的精确指向对各阵元通道幅相一致性提出了很高的要求,在实际的相控阵天线系统中,各阵元通道幅度和相位不可能完全保持一致,需要对阵列通道幅相误差进行实时地监测和校正。阵列单元校正的本质是对通道幅相误差的精确测量或估计,在现有幅相测量方法的基础上,提出一种全相位时移相位差算法。该算法需对存在时移关系的两输入序列分别进行全相位FFT,直接取主谱线的相位值无需校正即可得到输入信号的中间点相位信息,利用两序列主谱线的相位差求解信号的幅度值。由于全相位FFT具有"相位不变性",此方法能够很好地抑制频谱泄漏。仿真结果表明,该方法可有效避免第一类相位差法在不同步采样时误差较大的情形,测量结果明显优于第一类相位差法。     

太赫兹技术与在太赫兹波段的超光速研究

首先综述了太赫兹电磁辐射的性质和特点、太赫兹电磁辐射的产生和探测、以及太赫兹技术的应用.文章重点介绍了太赫兹波段的超光速研究进展,这里以介绍英国Strathclyde大学Klaas Wynne等人的若干实验结果为主.     

上海市白龙港片区污水治理南线工程简介

为缓解已建南干线、中线处理能力和实际处理负荷之间的矛盾,分担已建干线的输送压力,启动南线输送干线工程。通过对工程范围内水量预测、水力计算和各施工方案比选,本工程拟建设2根DN4000管道,采用顶管施工,输送至白龙港污水厂,解决浦西和浦东地区日益增加的污水问题,改善水域环境质量。     

一种低杂散低相位噪声频率合成器的设计

本文介绍了一种宽频带、捷变频、低相位噪声、低杂散的频率合成器,并对主要指标的进行了分析,实际设计的频率合成器达到了预期目标。在设计中,采用了微波电路计算机辅助设计(CAD)软件对部分电路进行了设计、优化和仿真,提高了设计效率和产品可靠性。     

Phase equilibria of HP–UHP mica-schists in Jiangling, Eastern Dabieshan orogen

The HP–UHP metamorphic terrane of Jiangling, eastern Dabieshan comprises extensively distributed granitic gneisses, mica-schists and numerous eclogite blocks. The mica-schists generally contain garnet, phengitic muscovite, biotite, plagioclase, quartz, rutile and a small amount of epidote and hornblende. Study on petrography and phases equilibria in the NCKMnFMASH system indicates that the present mineral assemblages in mica-schists are not in equilibrium. The earlier stage of mineral assemblage represented by garnet and phengite reflects a HP–UHP condition. The garnet compositions and the phengite Si contents give a PT condition of 580–600℃ at 2.6–2.8 GPa. The garnet zonation records an earlier progressive metamorphic process which may be associated with the appearance of glaucophane, jadeite and lawsonite. The later stage of mineral assemblage characterized by the presence of biotite and plagioclase reflects a PT condition of 620–635℃ at 0.9–1.1 GPa, belonging to the HP amphibolite facies. The main mineral assemblage in micaschists from the Jiangling region has recorded a complete HP–UHP metamorphic process.     

基于CPS的相位误差估计算法

在基于星座相位特征（CPS）相位误差估计算法的基础上,对高阶QAM信号,利用循环相关函数的局部对称性,提出一种基于局部对称性检测的相位误差估计算法。此外,利用平稳信号相关函数小波变换后的性质,提出了两种基于循环相关函数小波变换的相位误差估计算法。最后详细分析了小波变换对高斯白噪声的影响。与CPS算法相比,基于对称性检测的算法在低信噪比下有一定的优势。基于Morlet小波变换的相位误差估计算法在低信噪比下性能最好,而基于Harr小波变换的相位误差估计算法在高信噪比下性能较好。