PEMFC电催化剂利用率研究方法的探讨

提高电催化剂的利用率以降低质子交换膜燃料电池(PEMFC)的成本，是加速其商业化的一个重要途径。文中讨论了现有的CV法在研究PEMFC电催化剂利用率时存在的一些问题，如CV法扫描速度的影响及Pt理论比表面积难于准确确定等，为了较好地解决这一问题，提出了一种以单位质量电催化剂产生电池功率或电能来表示膜电极中电催化剂利用率的方法。     

一个一维非标准逆热传导问题的Fourier正则化方法

一维非标准逆热传导问题ut ux =uxx,u(1,t) =g(t) ,u(x ,0 ) =0 ,　0≤ x <∞ ,0 相似文献   

热传导问题的虚功原理方法

用虚功原理和变分方法讨论了热传导问题,指出力学中求解力场的方法同样适应于求热传导问题中的温度场。     

Structural Changes of Water Molecules Upon the Reduction of Quinones in The Reaction Center from Rhodobactery Sphaeroides

1 Results The photosynthetic bacterial reaction center (RC) is a membrane protein complex.The RC is composed of three protein subunits and redox components such as bacteriochlorophylls, bacteriopheophytins,and quinones.The RC performs the photochemical electron transfer from the bacteriochlorophyll dimer through a series of electron donor and acceptor molecules to a secondary quinone,QB.QB accepts electrons from a primary quinone,QA,in two sequential electron transfer reactions.The second electron trans...     

双门电冰箱的热传导问题

本文将根据热传导方程,对电冰箱达定态过程进行理论推导,以及定态后电冰箱单位时间吸收的热量,并由此计算出由于冰箱箱体的热量泄漏而消耗的能量。     

用扩展电阻法研究陶瓷微区电导性能

本文把扩展电阻法应用于陶瓷微区电导性能研究.建立了微区的定位标识系统,可精确、方便地对选定的微区进行电导性能及组分的重复测定.该方法在研究Ba(Sn_(1-x)Sb_x)O_3、ZnO及BaTiO_3半导体瓷应用中得到有意义的结果.     

Explicit analytical solutions of non-Fourier heat conduction equation for IC chip

Four basic explicit analytical solutions of non-Fourier heat conduction equation simulating IC chip thermal condition are derived. Some other analytical series solutions can also be derived with the above-mentioned basic solutions. Analytical solution has its own irreplaceable important meaning in theory. In addition, as the standard solution to check the accuracy, convergence and effectiveness of various numerical computational methods and their differencing schemes, grid generation ways and so on, the analytical solution is very useful also for the newly rapidly developing computational heat transfer.     

传热场问题的界面元法

用界面元法求解场问题,导出了求解三维不稳定温度场的界面元计算公式,这些公式适用于连续及不连续温度场,能反映介质可能存在的温度不连续性,较以往数值方法具有精度高、基本未知量少、适用于任意形状单元的优点,为温度场与位移场、应力场的耦合奠定了基础。     

Pathways of proton transfer in the light-driven pump bacteriorhodopsin

The mechanism of proton transport in the light-driven pump bacteriorhodopsin is beginning to be understood. Light causes the all-trans to 13-cis isomerization of the retinal chromophore. This sets off a sequential and directed series of transient decreases in the pK_a's of a) the retinal Schiff base, b) an extracellular proton release complex which includes asp-85, and c) a cytoplasmic proton uptake complex which includes asp-96. The timing of these pK changes during the photoreaction cycle causes sequential proton transfers which result in the net movement of a proton across the protein, from the cytoplasmic to the extracellular surface.     

冰箱试验包传热过程的仿真计算

建立了一个用于描述冰箱试验包传热过程的三维非稳态数学模型,模型考虑了试验包降温过程的物性变化,通过引入一个试验包边界导热系数折算因子来考虑由于其体积变化而造成的接触热阻.试验包的降温试验结果与预测值的比较表明:采用Morgan关联式计算试验包的表面传热系数精度较高,其值约为5～7W/(m2·K);试验包边界导热折算因子在10×10×10的网格划分下,其值约为0 1;试验包的温度预测值与实测值吻合得较好,模型可靠,可用于相变蓄能等类似问题的仿真计算.