某电解铅厂周边农田土壤和玉米中铅污染评价及同位素溯源研究

为探究铅在土壤-玉米-大气中的迁移转化行为,以某电解铅厂周边农田土壤和玉米为研究对象,采集距排烟口50 m、110 m、300 m、500 m、700 m、900 m和3 000 m处的土壤和玉米样品,利用原子吸收光谱仪(AAS)和电感耦合等离子体质谱仪(ICP-MS)分别测定土壤、玉米和大气样品的铅含量和同位素比值。结果表明:电解铅厂周边的玉米均受到铅的污染,玉米根中的铅主要来自土壤,籽粒中的铅很有可能大部分来自大气,少部分来自土壤,茎中的铅很可能来自土壤而不是叶面传输;籽粒中的铅与叶片中的铅具有显著的相关关系(P0.01),相关方程为y=-0.0002x~2+0.0461x-0.4643,R=0.966 7。     

利用反预报方法从截面预言近滴线丰质子核的结合能

在Origin等数据处理软件中,当实验数据较少时,自由参数的不同初始化设置会导致较大的结果差异,这为物理结果的确定带来较大不确定性.通过最小二乘法分析了345MeV/u ~(78) Kr+~9Be反应中产生的丰质子同位素的截面和结合能,并得到线性回归方程.通过回归方程,利用结合能预报部分丰质子核素的截面,以及通过实验截面对近质子滴线核素的结合能进行反预报测量.这对于近质子滴线的丰质子核素实验测量具有较好的借鉴意义.     

氧同位素标准样品的研制

使用高纯同位素物质精确配制同位素混合物,作为标准物,确定质谱仪器的系统误差。本工作用天然丰度水定量稀释高浓重氧水,制取从0.1982至96.92原子％~(18)O的氧同位素标准水样,用来校准质谱仪器。 实验采用BrF_5将水样转化成O_2。用质谱峰高法测定(18)~O和(17)~O丰度。比较质谱测定值和计算得到的丰度值C,求出质谱仪固有偏差校正系数K、并得到K与C的线性相关关系。 共得到16个具有准确丰度值的氧同位素标准水样。     

A model for carbon isotope distribution of methane during diagenesis

The evolution of methane carbon isotope with depth has been discussed based on diagenetic reaction kinetics and isotopic Rayleigh fractionational theory. A mathematical model to describe data of methane carbon isotope for the Liaohe oil field has been established.     

A continuous 200-ka palaeoclimatic record from stalagmite in Tangshan Cave, Nanjing

An oxygen isotope temperature record from 381 to 166 kaB. P. (²³⁰Th/²³⁴U dating and tuned ages) has been obtained by combining data on the isotopic composition of calcites with that of fluid inclusions trapped in a stalagmite from a limestone cave in which a fossil cranium deposited. Several laminae in microsequence of the stalagmite represent climatic events or shifts. The Nanjing man fossil was older than 381 kaB. P.     

Osmium isotope determination on mantle-derived peridotite xenoliths from Panshishan with N-TIMS

The¹⁸⁷Os/¹⁸⁸Os ratios of spinel lherzolite xenoliths from Panshishan determined with N-TIMS are lower than that of the primitive mantle, which shows depleted mantle characteristics. Their positive correlation with Al₂O₃/MgO suggests that the geochemical behavior of trace elements Re and Os is similar to that of Al₂O₃ and MgO respectively during the magmatic evolution and Re-Os isotopic system is largely immune to mantle metasomatism. A model age of 2.8–3.4 Ga obtained by¹⁸⁷Os/¹⁸⁸Os-Al₂O₃/ MgO correlation might represent the homogeneous age of the mantle lithosphere beneath the area.     

The neodymium isotopic characteristic and geological significance of Kuokesu plagioclase amphibolites from the Kuruktag, Xinjiang, China

The plagioclase amphibolites from Kuokesu area, Kuruktag, Xinjiang occur as enclaves embedded in the granodioritic gneiss. In the light of major elements and REE data, the parent rocks of the plagioclase amphibolites belong to weak_alkaline basalts. Their Nd model ages mainly range from 2 832 to 3 075 Ma. The seven plagioclase amphibolites yield a reasonable good isochron age of (828±86) Ma(2σ) with I Nd =0.510 981±82, ε Nd ( t )=-11.5±1.6. Such a case shows the existence of great proportion of the Archaean mafic crustal basement on the Kuokesu area. The strong tectonic_thermal event at about 820 Ma made the Sm_Nd isotope of the metamorphic rocks homogenization. This event would be associated with the Tarim Movement.     

Isotope composition of helium in eclogite from the Dabie Mountains, central China and its geological significance

Isotopic geochemical characteristics of helium in garnet and omphacite of eclogite in the Dabie Mountains are discussed. Concentrations of 3He and 4He in garnet and omphacite are 3.9×10 -14- 24.0×10 -14 and 0.48×10 -7-9.42×10 -7cm+3·g -1, respectively. Values of 3He/ 4He have a range of (1.19-4.63)×10 -7. Helium in the eclogite is derived from both mantle and crust. Isotopic geochemical data of helium indicate that eclogite in the Dabie Mountains might be formed in depleted mantle and the age of the cologite would be Indo-China epoch.     

石英的粒度对其前剂量热释光效应的影响

本文介绍了用石英粉末进行前剂量热释光效应的测量方法,并就不同粒度的石英样品对其１１０℃峰的ＴＬ响应的影响进行了专门研究。     

氧同位素：追踪陆架海沿岸水团变化的良好标志

对于陆架海而言除了冰体积效应,温度效应外,还有由于大陆淡水注入引起的,使δ＾１８Ｏ值负向偏移的效应,而且在低海平面时期,当沿岸水团盛行时,这种效应起主导作用。笔者将这种效应从广州的盐度效应中分离出来,称为陆架海的负值效应。