Preparing amphiphilic acidic zeolite via chemically coating alkylamine

Amphiphilic ODA/HY and ODA/ Hβ zeolites have been prepared via chemically coating octadecylamine (ODA) with alcohol as solvent. IR and titrimetric results indicate that ODA molecules are chemisorbed on the acidic sites in zeolite, showing the higher thermostability and alcohol-resistance. These am- phiphilic zeolites contain both the hydrophobic and hydrophilic groups, orient at the liquid-liquid phase-boundary in both cyclohexane/water and water/carbon tetrachloride systems, and exhibit the potential to be used in the phase-boundary catalysis and adsorption. No by-products with strong acid- ity are formed in this approach, therefore, it can be used to prepare amphiphilic acidic zeolites with low Si/Al ratio.     

西北地区居民生活碳排放结构及其影响因素

为揭示西北地区居民家庭生活碳排放现状与规律, 基于家庭生活碳排放相关数据的调查, 综合利用《IPCC国家温室气体清单指南(2006)》、《中国温室气体清单研究》、投入产出分析方法和生命周期评价方法, 对西北地区居民家庭生活碳排放情况进行了评估分析. 研究发现: 西北地区人均生活碳排放只有2.05 tCO₂/(人 年); 生活碳排放主要来源于煤炭、电力和食品消费, 化石燃料消费所产生的直接碳排放占39.29%, 电力等家庭消费活动所产生的间接碳排放占60.71%; 生活碳排放主要受地理环境、家庭规模、经济收入、年龄结构等因素影响, 不同省区和城乡人口之间的排放量存在一定差别.