～4.1 Ga xenocrystal zircon from Ordovician volcanic rocks in western part of North Qinlin80rosenic Belt

High-precision U-Pb dating by in situ LA-ICP-MS yields an age of 4079±5 Ma for a xenocrystal zircon from Ordovician volcanics of the Caotangou Group in western part of the North Qinling Orogenic Belt. As a result, the North Qinling Orogenic Belt becomes one of a few localities in the world that contain Hadean age records （4276±6 Ma and 4404±8 Ma detrital zircons from Jack Hill of the Yilgarn craton, 4016 Ma Acasta gneisses of the Wopmay Orogeny and Burang quartzite with detrital zircon of 4103 Ma in Tibet）. It is also the first report of the Hadean age in Phanerozoic volcanics. The finding of the 4.1 Ga xenocrystal zircon provides not only the geochronological record of the oldest crustal materials in China, but also the condition for further search for rocks forming in the region during the early time of the Earth＇s evolution. Thirty-six zircon U-Pb dates from the Ordovician volcanic rocks are subgrouped into seven generations that represent different tectono-magmatic events in the North Qinling Orogenic Belt. Among them, two periods of 0.9--1.5 Ga and 0.4--0.5 Ga are consistent with Mesoproterozoic and Early Paleozoic orogenies, respectively.     

Preparation and evaluation of biomimetric nano-hydroxyapatite-based composite scaffolds for bone-tissue engineering

In the present study,novel biomimetic composite scaffolds with a composition similar to that of natural bone were prepared,using nano-hydroxyapatite,collagen,and phosphatidylserine.The scaffolds possess an interconnected porous structure with a porosity of 84%.The pore size ranges from several micrometers up to about 400 m.In-vitro studies in simulated body fluids showed that the morphologies of the products derived from mineralization can be regulated by the extracellular matrix components of the scaffolds;this in turn leads to creation of a large number of hydroxyapatite crystals on the scaffold surface.The regulatory properties of collagen and phosphatidylserine also influenced the cell response to the composite scaffolds.MC3T3-E1 cells attached and spread on the surfaces of the materials and interacted with the substrates;this may be the result of charged groups on the composite materials.Radiological analysis suggested that calluses and bone bridges formed in defects within 12 weeks.These composite scaffolds may therefore be a suitable replacement in bone-tissue engineering.     

U-Pb ages and Hf isotopes for detrital zircons from quartzite in the Paleoproterozoic Songshan Group on the southwestern margin of the North China Craton

In situ U-Pb dating and Lu-Hf isotopic analysis were carried out for detrital zircons from quartzite in the Paleoproterozoic Songshan Group on the southern margin of the North China Craton （NCC）. The results provide further constraints on the crustal formation and evolution history of NCC. Four ^207Pb/^206Pb age populations were obtained from 99 analyses, with clusters at -3.40 Ga, 2.77-2.80 Ga, -2.50 Ga and 2.34 Ga, respectively. The 3.40 Ga old zircons have similar Hf isotopic compositions to those from Archean rocks in the Jidong and Anshan areas of NCC. However, crustal remnants older than 3.6 Ga have been identified in the southern margin of NCC, the South China Craton, the northwestern part of the Qinling Orogen and its adjacent area. Thus, it is not easy to trace the source rock from which the 3.40 Ge detrital zircons were derived. It can be inferred that the crustal remnants older than 3.40 Ga might have been widely distributed in the North China Craton. The 2.77-2.80 Ga zircons make up a relatively small proportion and have the highest εHf（t） values （up to 6.1±1.6）, consistent with the Hf isotopic composition of the depleted mantle at 2.83 Ga. Their single-stage Hf model age of 2.83 Ga is close to their crystallized age, suggesting that their source rocks were extracted from the contemporaneous depleted mantle. The -2.50 Ga zircon grains constitute about 85% of the total grain population and their Hf isotopic compositions indicate major growth of juvenile crust at -2.50 Ga but minor reworking of ancient crust. The youngest zircon dated in this study gave an U-Pb age of 2337±2.3 Ma, which can be considered the maximum depositional age of the formation of the Songshan Group.     

基于深度特征提取神经网络的滚动轴承故障诊断

滚动轴承作为旋转机械的重要组成部分,其运行安全性受到大量关注,但传统的基于信号处理的时频分析故障诊断方法较为依赖专家知识从而难以广泛应用。结合应用较广的卷积神经网络和长短时记忆网络模型的优点-自动提取振动信号的深层特征信息以及可识别所提取的长时连续的振动信号时序特征信息,提出一种深度特征提取神经网络模型,将原始的振动信号作为模型输入,进而通过多层卷积与长短时记忆网络对振动信号进行故障特征信息提取,可以有效提取滚动轴承振动信号中的深层时序故障特征信息,进而准确辨识滚动轴承不同的故障模式,并且避免了复杂的信号预处理与人工进行信号特征提取的过程。通过凯斯西储大学滚动轴承故障实验的10类健康状态数据验证了所提方法的有效性,并对实验结果进行分析,解释了在迭代过程中出现精度波动的可能原因。     

黑龙江金厂金矿花岗斑岩锆石地球化学、U-Pb年代学及地质意义

为确定与金厂金矿成矿有关的岩浆类型、活动时限和构造背景,采用LA-ICP-MS技术对研究区花岗斑岩开展了锆石U-Pb年龄及原位微区微量元素测定。结果表明:锆石环带发育,wTh/wU值>0.4,具有岩浆锆石特征;锆石年龄分布于220Ma和103～123Ma 2个区间,代表了2期岩浆事件;对2种锆石分别命名为捕获岩浆锆石和新生岩浆锆石;锆石的地球化学和年龄信息显示捕获岩浆锆石的原岩为早三叠世花岗岩;锆石微量元素信息暗示花岗斑岩是早三叠世花岗岩高度熔融结晶分异、侵位于浅部氧化环境而形成,这一过程导致新生岩浆锆石负Eu异常程度降低。新生锆石加权平均年龄为(113.5±3.8)Ma,与成矿年龄一致,据此认为早白垩世的岩浆事件是金厂金矿成矿事件的直接原因,成矿背景为太平洋板块俯冲后的岩石圈伸展。     

修正混合规则的BWRS型状态方程及其在CO2-原油体系相态计算中的应用

CO2-原油体系中含有非烃和较多重组分,非理想性较强。以对非理想体系有较好计算效果的BWRS状态方程为基础,考虑温压条件和组分间的相互作用,修正混合规则,使其更加适用于CO2-原油体系的相态计算,提高方程的预测精度。应用油田现场油样实测气液相组分数据,以三参数PR和PT方程的计算均值代表常用状态方程,分别采用基于修正混合规则的BWRS方程和常用状态方程对油气组分和密度等参数进行计算。结果表明:修正混合规则的BWRS方程中各混合参数都可还原为维里系数对组分的依赖形式,理论性更强;方程计算精度显著提高,对非烃类气体和重组分有较好的适应性,能满足工程应用要求。     

四旋翼飞行器全局动态鲁棒性跟踪控制

针对带有模型参数不确定和风微扰状况的四旋翼飞行器轨迹跟踪问题,提出了一种全局动态鲁棒性控制策略. 基于牛顿-欧拉形式化方法解耦得到飞行器直线运动部分和旋转姿态控制部分. 设计了模型预测控制器来实现直线运动部分的动态实时控制. 并在模型参数不确定和风微扰情况下,为了稳定四旋翼飞行器的旋转姿态行为和直线运动,引入全局鲁棒滑模控制方法. 仿真结果表明,设计的全局动态鲁棒控制策略具有实时快速稳定的跟踪效果.      

Crustal growth at ～2.5 Ga in the North China Craton：evidence from whole-rock Nd and zircon Hf isotopes in the Huai＇an gneiss terrane

The Huai’an gneiss terrane mainly consists of TTG gneisses and dioritic gneisses. Laser in situ U-Pb dating of magmatic zircon cores indicates that protolith of these gneisses was formed at ~2.5 Ga. The TTG gneisses have positive εNd（t） values of 2.7 to 4.3, and most of the magmatic zircons have positive εHf（t） values of 2.0 to 8.3. These positive εNd（t） and εHf（t） values are both similar to those of the contemporaneous depleted mantle at 2.5 Ga. Moreover, the young Hf model ages of 2.44 to 2.73 Ga for the magmatic zircons are close to the timing of the zircons growth. The whole-rock εNd（t） values are lower in the dioritic gneisses （0.8 to 1.7） than in the TTG gneisses due to the involvement of ancient crust in its source. However, many magmatic zircons from the dioritic gneisses have similar εHf（t） values （2.0 to 7.9） to that of the coeval depleted mantle; their Hf model ages of 2.49 to 2.75 Ga are close to the U-Pb ages of zircons. The highest εHf（t） values are close to the value of the depleted mantle, and the relatively high εHf（t） values corresponds to the relatively young Hf model age. These Nd and Hf isotope features suggest that these two types of gneisses of the Huai’an gneiss terrane originated from the juvenile crust at ca. 2.5 Ga.     

黄芩黄酮成分分析及牛血清白蛋白结合活性成分筛选

目的 分析鉴定陕西地区黄芩粗提物中的黄酮类成分,并筛选出其中具有牛血清白蛋白(BSA)结合活性的成分.方法 使用UPLC-Q-TOF-MS/MS对黄芩粗提物中的黄酮类成分进行分析,并结合ESI-M S质谱裂解途径解析进行鉴定,借助亲和超滤技术筛选出其中的BSA结合活性成分.结果 从黄芩粗提物中共鉴定出33种黄酮类成分,包括21种黄酮苷元与12种黄酮苷类,详细分析了其在ESI源下的质谱碎片裂解规律,并从中筛选出17种BSA结合活性成分,包括2',3,5,6',7-五羟基黄烷酮、2',5,6',7-四羟基黄烷酮、白杨素-7-O-β-葡萄糖苷等.结论 初步明确了陕西地区黄芩中黄酮类成分的化学组成,归纳了其ESI裂解规律,并筛选出其中的BSA结合活性成分.为陕西地区黄芩资源的开发利用以及中药现代化提供科学依据.     

LA-(MC)-ICPMS U-Pb zircon geochronology and Lu-Hf isotope compositions of the Taihua complex on the southern margin of the North China Craton

Widely distributed on the southern margin of the North China Craton, the Taihua complex extends roughly in an east-west direction and the relatively complete successions are found in Lushan County, Henan Province. Like many other Archean terranes, the Taihua Complex can be divided into two major lithological units along the Dangze River, namely gneisses series and supracrustal rocks. The former is located on the north side of the river and chiefly composed of TTG gneisses and amphibolites; the latter on the south side of the river is mainly supracrustal rock. Coupled with the previous studies, the results obtained by this study show that the Taihua complex was formed in a large time span from Neoarchean to Palaeoproterozoic. The TTG gneisses and amphibolites are dated at Neoarchean (2794–2752 Ma). The 2.9 Ga and 3.1 Ga zircons in amphibolites could be xenocrysts. In the North China Craton, the 2.8–2.7 Ga old rocks crop out in several areas e.g. western Shandong Province, Jiaodong Peninsula and Lushan area of Henan Province. In addition, 2.8–2.7 Ga detrital zircons or xenocryst zircons have been recognized in Huai’an, Fuping, Wutai areas of North China Craton and also reported in the Early Paleozoic diamondiferous kimberlites in Mengyin and Fuxian. All these age results indicate that the 2.8–2.7 Ga rocks may have been developed much broader region than today’s outcrops. Zircon Hf and whole rock Nd isotopes show that the 2.8–2.7 Ga tectono-thermal event represents an important period of crustal growth with minor ancient crust reworked in the North China Craton. However the formation of supracrustal rocks is limited to 2.2–2.0 Ga in the Palaeoproterozoic time, not the Archaean, as previously believed. Combined with the chronological data of aluminium-rich metamorphic rocks (Khondalite series) on the southern margin of the North China Craton and adjacent areas, it is suggested that the above areas have widely developed Paleoproterozoic passive continental margin environment.