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The chemical composition, molecular weight and its distribution, the bonding structure and the regulation of ultrahigh molecular weight polyacrylonitrile (UHMW-PAN) prepared by aqueous suspension polymerization were determined by FIIR, viscometry, GPC, ^3H-NMR and ^13CNMR. The mechanical properties of the porous hollow fiber prepared by UHMW-PAN were discussed to provide a theoretical basis for the preparation of ideal precursors of the porous hollow oxidation fiber.  相似文献   
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