Effect of Co substitution on the structural,dielectric and optical properties of KBiFe2O5

Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample.     

平面波斜入射空间光调制器对产生完美涡旋光束的影响

研究了平面波斜入射空间光调制器(SLM)时完美涡旋光束的变化。结合螺旋相位与锥透镜透过率函数设计相位掩模板,在SLM的傅里叶平面上产生完美涡旋光束。所产生的涡旋性质通过调控完美涡旋光束±1级干涉得到了验证。改变平面波照射在SLM上的入射角,完美涡旋光束离心率与平面波入射角为线性函数关系,相关系数高达0.986 72。此外,随着平面波入射角增大,完美涡旋光束总光强也随之变弱。     

霍比特人3:五军之战

导演:彼得·杰克逊 编剧:弗兰·威尔士/菲利帕·鲍恩斯/彼得·杰克逊/吉尔莫·德尔·托罗/J·R·R·托尔金 主演:马丁·弗瑞曼/伊恩·麦克莱恩/理查德·阿米蒂奇/伊万杰琳·莉莉/李·佩斯 剧情简介 被吵醒的史矛革大闹长湖镇,最终为人类巴德射杀.索林·橡木盾多年的夙愿终于实现,孤山埃尔波尔重新回到矮人手中.     

加强医院绩效核算及管理的措施分析

降低成本是医院开展绩效管理工作的关键，绩效管理能够从本质上提升医用物资使用效率，同时，提升医院的竞争能力和医疗水平，社会效益和经济效益相比较，社会效益更为重要。因此，医院的绩效核算工作应坚持考核指标与绩效联系，职工付出与绩效联系，进而建立起十分严格的绩效考核机制。在医院绩效管理过程中，需要医院领导高度重视，各个科室也要及时沟通，紧密联系。该文中，笔者就加强医院绩效核算及管理的措施进行分析。     

超临界CO2气溶胶溶剂萃取法制备尤特奇S100纳米颗粒

采用超临界CO2气溶胶溶剂萃取法(ASES)制备了尤特奇S100(Eudragit S100)纳米粒,考察了有机溶剂的选择、压力、温度、溶液浓度及流速等主要工艺参数对Eudragit S100纳米粒形貌及粒径大小的影响,并采用扫描电镜、傅立叶红外光谱分析对结果进行了表征。结果表明,在以丙酮作为溶剂、压力为16 MPa、温度为45℃、溶液浓度为1 mg/m L的工艺条件下,可制备出有机溶剂残留少、分布均匀、平均粒径为30~60 nm的Eudragit S100纳米颗粒。纳米粒子的平均粒径随温度、压力的升高而减小,随溶液浓度的减小而减小。     

模拟结果为什么比实际更暖:简化气候模型结果（英文）

设计了一个非专业人士能够使用、最简化的气候敏感模型,用来研究人类活动所导致的全球变暖的幅度问题.在1990年的第一次IPCC评估报告中,IPCC对其报告中预测的未来全球变暖幅度很有信心,但是随后的观测结果显示全球的变暖幅度只有预测的一半.而自2001年起,全球变暖出现停滞,但是仅仅考虑到二氧化碳浓度的增加,很少有模型能够模拟出这一变化.在已出版的IPCC第五次评估报告的草稿中,IPCC大幅度削减了近期变暖的幅度,并以专家评估代替了模型预测.但是报告中关于未来气候长期变化的预测仍被保留.如果把IPCC模型的总反馈从1.9 W m–2 K–1调整到1.5 W m–2 K–1,气候敏感模型中模拟的温度将从3.2 K降至2.2 K.同时由于反馈很可能是净负反馈,更合适的估计应该是1.0 K.1.0 K是一个能够实现的增幅,21世纪的实际变暖将会小于1 K.即使燃烧所有可开采的化石燃料也不会使全球变暖的幅度超过2.2 K,这一增加幅度也将趋于平稳.本文认为解决IPCC第四、五次报告中评估方法的差异非常关键.一旦这些差异得到解决,人类活动导致的全球变暖在22世纪以及几个世纪以后的平稳态将有可能不会超过IPCC当前模型预测的1/3~1/2.     

Vertically aligned ZnO nanorods on porous silicon substrates: Effect of growth time

Vertically aligned ZnO nanorods were successfully grown on porous silicon(PS) substrates by chemical bath deposition at a low temperature.X-ray diffraction, field-emission scanning electron microscopy(FESEM), transmission electron microscopy(TEM), and photoluminescence(PL)analyses were carried out to investigate the effect of growth duration(2 h to 8 h) on the optical and structural properties of the aligned ZnO nanorods. Strong and sharp ZnO(0 0 2) peaks of the ZnO nanorods proved that the aligned ZnO nanorods were preferentially fabricated along the c-axis of the hexagonal wurtzite structure. FESEM images demonstrated that the Zn O nanorod arrays were well aligned along the c-axis and perpendicular to the PS substrates regardless of the growth duration. The TEM image showed that the top surfaces of the ZnO nanorods were round with a smooth curvature. PL spectra demonstrated that the ZnO nanorods grown for 5 h exhibited the sharpest and most intense PL peaks within the ultraviolet range among all samples.     

Effect of equal channel angular pressing on aging treatment of Al-7075 alloy

The effect of aging treatment on microstructure and mechanical properties of equal channel angular pressed Al-7075 alloy was examined.Commercial Al-7075 alloy in the solid solution heat-treated condition was processed by equal channel angular pressing through route BCat both the room temperature and 120 1C. Only three passes of equal channel angular pressing was possible due to the low ductility of the alloy at both temperatures. Followed by equal channel angular pressing, the specimens have been aged at 120 1C for different aging times. Mechanical properties were measured by Vickers microhardness and tensile tests and microstructural observations were undertaken using transmission electron microscopy, X-ray diffractometer as well as optical microscopy. Microstructural investigations showed that ultrafine-grained materials with grain size in the range of 200–350 nm and 300–500 nm could be obtained after three passes of equal channel angular pressing at room temperature and 120 1C, respectively. Equal channel angular pressing of solid solution heat-treated Al-7075 alloy accelerates precipitation rate and subsequently leads to a significant decrease in aging time to attain maximum mechanical properties. Furthermore, it is possible to achieve maximum mechanical properties during equal channel angular pressing at 120 1C as a result of dynamic aging and formation of small η′ phase.     

新疆油田低渗透区块空气驱实验研究

低渗透油藏由于地层能量衰竭较快且注水困难,一次及二次采收率较低,故考虑采用注空气技术来维持地层压力、提高采收率.相对于其他气驱技术,空气驱具有来源广、成本低的显著优势.通过对C-9井区原油低温氧化实验及空气驱实验,研究了目标区块原油的低温氧化特性及油藏条件下的空气驱提高原油采收率幅度.主要从注空气安全和提高采收率潜力方面评价了空气驱低温氧化工艺的可行性.实验结果表明,在相对低温条件下C-9区块原油可以有效消耗氧气,即使氧化速率缓慢,但是考虑空气在油藏中滞留时间及氧化反应的热效率,仍可以保证注气安全,空气驱二次采油可以得到较高的采收率,但是对于剩余油饱和度低的三次采油,空气驱提高采收率的幅度相对较低.     

林果业生产机械化水平评价与实证研究

为掌握多年生作物林果业的生产机械化发展现状,十分有必要建立一套指标体系来评价其生产机械化水平.从统计具有可操作性角度出发,对林果业概念界定、指标及权重设置、评价方法建立等方面进行了深入探讨.通过典型调查与专家咨询、定性与定量研究相结合等方法,从林果业全程生产的15项作业中重点考虑作业频次高、用工量大、作业费用多、机械化需求迫切的重点作业项目,选取了中耕、施肥、植保、修剪、采收、田间转运等6项,设置了相应评价指标,用德尔菲法确定了指标权重,构建了评价指标体系,采用线性加权综合评价法进行计算和评价.最后进行了应用验证,结果表明该指标体系能一定程度反映生产实况,且具有可操作性,为分区分类指导我国林果业生产机械化发展提供了科学依据.