Necking Point in PET High-speed Fiber Spinning

Cross-over method is established to predict necking point for PET high-speed fiber spuming. Even slowly crystallizing polymers such as PET can crystallize on the spinline at sufficiently high spinning speed. The development of running velocity, temperature, crystallinity and rheological force is investigated for the take-up velocity over a range of 6 000 - 10 000 m/min. The pos-ition of necking point, temperature rise and abrupt increase of crystallinity move closer to the spinneret with the increase of take-up velocity.     

Optimization of the Arrangement of Mixing Sheets in VK Tube

The flow mechanism of Nylon-6 melt over perforatedbaffles with conical shape in the VK tube is explained bycomputerized analysis based on a rational assumption ofStokes’flow.The governing equations for a two-dimen-sional flow are solved by finite difference method to gen-erate the stream function profile,velocity field and resi-dence time distribution.Optimization of the geometriesof the baffle structure brings about a uniform residencetime distribution of the melt,so as to ensure a homoge-neous extent of reaction for the final product.Furthertheoretical investigation shows that dead zones areformed and that a rule of thumb has to be practiced fortheir elimination.     

Polyamide-6 Polymerization in the VK Tube Reactor with Baffle Structure

The melt flow mechanism of polyamide-6 (PA6) was simulated with the mathematical flow model and tested by Particle Image Velotrimitry (PIV) . The complete mathematical model for PA6 polymerization while flowing through the VK tube reactor was established according to PA6 hydrolytic polymerization kinetics. The characteristic data such as residence time, caprolactam conversion and the degree of polymerization (D. P.), at every stage of polymerization reaction and at every point of the VK tube were presented for the melt flowing through ten alternate conical baffles in VK tube.     

含丝素蛋白膜对茶多酚的缓释作用

研究丝素蛋白及丝素蛋白/二氧化硅纳米杂化材料的两种药膜对天然抗菌药——茶多酚的缓释性能,并应用到聚丙烯无纺布的功能性后整理中.用体外释药方法测定了含茶多酚的两种药膜对茶多酚的缓释性能,并使用扫描电镜观察整理前后聚丙烯无纺布表面形态变化.结果表明,两种丝素蛋白膜都可以作为茶多酚的控制释放材料,丝素蛋白/二氧化硅纳米杂化药膜的控制释放作用优于丝素蛋白药膜.整理到聚丙烯无纺布上的上述两种药膜仍具有一定的缓释作用.     

尼龙66的多重熔融行为

研究了尼龙66的双重熔融峰的转变行为。高温峰(峰1)的熔融温度几乎不变,低温峰(峰2)的熔融温度随着退火时间的延长逐渐升高。全部退火时间内双峰的总面积保持不变,而高温峰、低温峰的相对面积比变小。高温峰被认为来自于熔体的快速冷却(动力学优先),低温峰则来自于缓慢冷却(热力学优先)。低温峰向高温峰的转变是由于不同的结晶尺寸和/或完善程度引起。     

PET固相聚合反应机理及动力学模型

综述了PET固相聚合早期的和20世纪90年代以后出现的反应机理和动力学模型，指出了这些反应机理和动力学模型可能存在的一些问题，为形成更深入，更全面的动力学模型打下了基础。     

具有优化的斜挡板内部结构的VK管中尼龙6聚合反应的数学模拟研究

在尼龙6水解聚合数学模型得到实验验证的基础上,模拟熔体流过VK管10块挡板的过程中单体的转化率、产物的聚合度、环状二聚体的含量、大分子的端基浓度、相对分子质量多分散性指数等重要质量指标随时间和位置的变化规律,从聚合指标的计算结果反证挡板结构的合理性.     

尼龙6水解开环聚合模型及其验证

根据尼龙6水解聚合反应机理,建立了完整的聚合反应数学模型,采用龙格-库塔法计算出各聚合变量的初值,修正的哈明预测校正法求出各种聚合变量的终值,并用实验测定数据验证尼龙6水解聚合模型的可靠性。为进一步研究具有锥形斜挡板内部结构的VK中尼龙6聚合反应奠定基础。