剪切改性对长链支化聚丙烯流变性能的影响

利用密炼机对长链支化聚丙烯（LCB-PP）施加剪切,通过改变密炼机转子转速、物料在密炼机中的停留时间,得到了具有不同剪切历程的样品。采用熔体流动速率（MFR）、挤出胀大比（SR）以及动态流变特性等表征方法,研究了剪切改性对于LCB-PP流变性能的影响规律。结果表明,施加剪切历程会使LCB-PP的MFR变大,SR变小,造成低频下的储能模量和复数黏度减小;并且剪切历程越长,流变性能下降越明显。另外,末端效应和Cole-Cole图等的分析结果也证明了剪切改性过程中长支链发生解缠结和取向现象。     

Magnetostratigraphy of the Zanda basin in southwest Tibet Plateau and its tectonic implications

The Zanda basin is one of the very important basins at the north slope of the Himalaya Range. Thus the study of the basin strata will provide critical information about the tectonic evolution of the Himalayan Orogenic Belt. 268 oriented block samples were collected in the 750-m-thick sections of the Zanda basin. The characteristic remanent magnetization （ChRM） was isolated that decays linearly to the origin between 500℃ and 690℃for most studied samples. An age range of 9.5-2.6 Ma was estimated from the correlation between our observed polarity column and the Geomagnetic Polarity Time Scale （GPTS）. The age of the Zanda basin does not support the models that the South Tibetan Detach system （STDS） is one of the basin controlling faults. Given the sedimentological features in the basin and the tectonic features at the north edge of the basin, the Zanda basin was a half graben that was possibly controlled by the Karakorum fault on the northeast.     

枯草芽孢杆菌寡聚-1,6-葡萄糖苷酶基因在毕赤酵母中的表达研究

根据枯草芽孢杆菌（Bacillus subtilis）寡聚-1,6-葡萄糖苷酶基因序列设计引物,以pHBM003为模板,扩增得到寡聚-1,6-葡萄糖苷酶基因,克隆至毕氏酵母（Pichia pastoris）表达载体pHBM905上,获得重组毕氏酵母表达载体pHBM9053．将此质粒分别转化毕氏酵母GS115、KM71和SMD1168菌株,筛选获得重组毕赤酵母GS115（pHBM9053）、KM71（pHBM9053）和SMD1168（pHBM9053）;然后进行摇瓶诱导培养,这3株毕氏酵母分别在诱导培养60h、48h和24h后,酶活力达到最高,对应为2．233u／mL、0．34u／mL和1．235u／mL;GS115（pHBM9053）所产寡聚-1,6-葡萄糖苷酶的最适反应温度为75℃,最适反应pH值为6,在30～75℃、pH8～9范围内较稳定．     

Characteristics of hydrocarbon accumulation and exploration potential of the northern South China Sea deepwater basins

Although the huge potential of the northern South China Sea deepwater basins has been proven by a series of discoveries that followed the exploration breakthrough of well LW 3-1-1, recent drilling and other studies have demonstrated the uniqueness and complicated nature of hydrocarbon accumulations of the deepwater basins there. Based on a review of previous work and the latest exploration activities and studies, the purpose of this paper is to discuss the critical controls for hydrocarbon accumulations in the deepwater basins of the northern South China Sea. A terrestrial-marine transitional coal-bearing source rock is proposed to be the primary source rock for the deepwater basins. A marine source rock, which was first identified as contributing to hydro-carbon generation in this region, probably plays a significant role in the deep-and ultra-deep water basins south to the Pearl River Mouth and Qingdongnan basins. The shelf margin delta depositional systems in the Baiyun Sag, sourced from the Pearl River, are currently primary exploration targets in the deepwater part of the Pearl River Mouth Basin, whereas the western Red River delta-ic-submarine fan depositional systems, initially proven by drilling, are the possible major exploration reservoirs in the Qing-dongnan deepwater areas. Current deepwater exploration targets at the large-sized structural traps and deep and ultra-deep areas in the south of the Pearl River Mouth and Qingdongnan basins will be the future exploration focus. Deepwater exploration activities and relevant fundamental studies, supporting and promoting each other, are of great importance to the national energy supply of China, the basic regional studies of the South China Sea, advancements in technology, and development of related deepwater industries, and will safeguard national sovereignty and territorial integrity.     

Isotopic composition of organic carbon and elemental carbon in PM2.5 in Hangzhou, China

In order to identify the sources of organic carbon (OC) and elemental carbon (EC) in airborne PM2.5 in Hangzhou, OC and EC were oxidized to CO2 offline in two thermal steps, and their carbon isotope compositions were measured by mass spectrometer. Results showed that the average δ13COC values were -52.8‰, -48.1‰, -50.0‰ and -52.5‰ in spring, summer, autumn, and winter, respectively, and the annual average value was -50.9‰ (-85.0‰ to -35.6‰), whereas δ13CEC values were -26.4‰, -26.9‰, -26.7‰ and -25.9‰ in the four seasons, and its annual value was -26.5‰ (-30.5‰ to -23.8‰). Large differences were found between isotope compositions of the two types of carbon. δ13COC values were much smaller than those of δ13CEC, and varied in a large range, and the ratios in both spring and winter were the smallest. δ13CEC varied in a small range, and its mean values in four seasons were nearly the same. This suggests that the carbon isotope compositions of OC and EC in PM2.5 can provide useful information in distinguishing their sources.     

采用离子热方法合成夹心型钨磷酸盐

采用离子热方法在离子液体[Emim]Br(1-乙基-3-甲基咪唑溴盐)中合成了夹心型的钨磷 酸盐H₃(Emim)₇[Ni₄(Mim)₂(PW₉O₃₄)₂]·4H₂O(1)(Mim 为乙基咪唑). 通过X 射线衍射、元素分析、 红外光谱、热重、XRD、电化学和光催化等对该化合物的结构和性质进行了测试和表征. X 射 线单晶衍射分析表明: 化合物1 属单斜晶系, C2/c 空间群, 晶胞参数: a = 35.584(7) Å, b = 14.513(3) Å, c = 24.423(5) Å, α= 90.000°, β= 101.38(3)°, γ= 90.000°, V = 12365(4) ų, Z = 4. 在化 合物1 的晶体结构中, 阴离子框架为2 个乙基咪唑分子修饰的有机无机杂化夹心型阴离 子[Ni₄(Mim)₂(PW₉O₃₄)₂]^10-, 而且多酸阴离子的表面氧原子与游离的抗衡阳离子1-乙基-3-甲基 咪唑之间存在着广泛的C-H···O 氢键作用, 进而构筑成为一个三维的超分子框架.