Spin crossover and iron-rich silicate melt in the Earth's deep mantle

A melt has greater volume than a silicate solid of the same composition. But this difference diminishes at high pressure, and the possibility that a melt sufficiently enriched in the heavy element iron might then become more dense than solids at the pressures in the interior of the Earth (and other terrestrial bodies) has long been a source of considerable speculation. The occurrence of such dense silicate melts in the Earth's lowermost mantle would carry important consequences for its physical and chemical evolution and could provide a unifying model for explaining a variety of observed features in the core-mantle boundary region. Recent theoretical calculations combined with estimates of iron partitioning between (Mg,Fe)SiO(3) perovskite and melt at shallower mantle conditions suggest that melt is more dense than solids at pressures in the Earth's deepest mantle, consistent with analysis of shockwave experiments. Here we extend measurements of iron partitioning over the entire mantle pressure range, and find a precipitous change at pressures greater than ～76?GPa, resulting in strong iron enrichment in melts. Additional X-ray emission spectroscopy measurements on (Mg(0.95)Fe(0.05))SiO(3) glass indicate a spin collapse around 70?GPa, suggesting that the observed change in iron partitioning could be explained by a spin crossover of iron (from high-spin to low-spin) in silicate melt. These results imply that (Mg,Fe)SiO(3) liquid becomes more dense than coexisting solid at ～1,800?km depth in the lower mantle. Soon after the Earth's formation, the heat dissipated by accretion and internal differentiation could have produced a dense melt layer up to ～1,000?km in thickness underneath the solid mantle. We also infer that (Mg,Fe)SiO(3) perovskite is on the liquidus at deep mantle conditions, and predict that fractional crystallization of dense magma would have evolved towards an iron-rich and silicon-poor composition, consistent with seismic inferences of structures in the core-mantle boundary region.     

A crystallizing dense magma ocean at the base of the Earth's mantle

The distribution of geochemical species in the Earth's interior is largely controlled by fractional melting and crystallization processes that are intimately linked to the thermal state and evolution of the mantle. The existence of patches of dense partial melt at the base of the Earth's mantle, together with estimates of melting temperatures for deep mantle phases and the amount of cooling of the underlying core required to maintain a geodynamo throughout much of the Earth's history, suggest that more extensive deep melting occurred in the past. Here we show that a stable layer of dense melt formed at the base of the mantle early in the Earth's history would have undergone slow fractional crystallization, and would be an ideal candidate for an unsampled geochemical reservoir hosting a variety of incompatible species (most notably the missing budget of heat-producing elements) for an initial basal magma ocean thickness of about 1,000 km. Differences in 142Nd/144Nd ratios between chondrites and terrestrial rocks can be explained by fractional crystallization with a decay timescale of the order of 1 Gyr. These combined constraints yield thermal evolution models in which radiogenic heat production and latent heat exchange prevent early cooling of the core and possibly delay the onset of the geodynamo to 3.4-4 Gyr ago.     

A doubling of the post-perovskite phase boundary and structure of the Earth's lowermost mantle

The thermal structure of the Earth's lowermost mantle--the D' layer spanning depths of approximately 2,600-2,900 kilometres--is key to understanding the dynamical state and history of our planet. Earth's temperature profile (the geotherm) is mostly constrained by phase transitions, such as freezing at the inner-core boundary or changes in crystal structure within the solid mantle, that are detected as discontinuities in seismic wave speed and for which the pressure and temperature conditions can be constrained by experiment and theory. A recently discovered phase transition at pressures of the D' layer is ideally situated to reveal the thermal structure of the lowermost mantle, where no phase transitions were previously known to exist. Here we show that a pair of seismic discontinuities observed in some regions of D' can be explained by the same phase transition as the result of a double-crossing of the phase boundary by the geotherm at two different depths. This simple model can also explain why a seismic discontinuity is not observed in some other regions, and provides new constraints for the magnitude of temperature variations within D'.