Studies on syntheses of biscrown ether compounds

Multi-ester type biscrown ether compound(I) was prepared by the reaction of 6-bromoacetacetic ester dibenzo-16-crown-5(7) with phenyl-methyl ether-2,6-diformic acid potassium salt in anhydrous DMF at refluxed temperature, and color biscrown ether compound(II) was prepared by the reaction of 4′-aminobenzo-15-crown-5(12) with 2,2′(O-formoyl naphthyl)ethyl ether (9) in anhydrous ethanol at 40 C under N₂. New compounds(I, II) were characterized by IR,¹H NMR, MS and elemental analysis. Supported by the National Natural Science Foundation of China Niu Changrong: born in December, 12, 1938, Professor     

Cobalt doped titanate nanotubes: Synthesis and properties

Cobalt oxide doped titanate nanotubes are synthesized with a simple hydrothermal treatment of mixed Co_3O_4 and TiO_2 powders. The formed tubular nanostructure, chemical composition,and the elemental distribution are analyzed using TEM, BET, FTIR, XRD, and XPS. The electrocatalytic activity towards oxygen evolution reactions and photodegradation against Rhodamine B are investigated. It has been found out that the oxygen evolutions starts at 0.8 V and reaches 0.98 mA ·cm~(–1) at 1.4 V vs. SCE. For photodegradation of Rhodamine B, the concentration decreased to 24% after 1 h irradiation using the sample with a mass percentage of 5% cobalt. The results demonstrate that the cobalt oxide doped titanate nanotubes are good candidates as electrocatalysts and photocatalytic materials.     

超载、高温条件下半刚性基层沥青路面车辙试验研究

采用车辙试验检验沥青路面抗车辙能力的方法,介绍了沥青混和料车辙试验的试验过程,并分析了高温和超载对动稳定度的影响,最后对减小车辙病害提出了建议。     

企业发出商品管理信息系统的实现

本文介绍了山东文登市布鞋工业集团公司发出商品管理信息系统的分析、设计与实现。     

取用水监测点的水量计算与变化趋势分析

加强取用水监测是实施最严格水资源管理制度的重要举措.为了更有效地利用大量的取用水在线监测数据,需要对获取的监测数据进行预处理.本文首先提出应用中位数法与曲线拟合相结合的方法对取用水监测数据进行异常值检测,再用曲线拟合方法对异常值进行校正;其次,根据校正后得到的数据进行两个方面的分析,一方面是计算监测点的年取水量,另一方面是应用集成经验模态分解方法分析监测点的日取水量变化趋势;最后,以M市的16个自来水厂2016年取用水在线监测数据为例进行实证分析,结果表明,本文提出的中位数法与曲线拟合相结合的方法能够有效地检测异常值,进而再用曲线拟合方法能够更好地对异常值校正.根据校正后得到的数据进行分析发现81%的监测点年取水量相对2011年水利普查数据有所增加,个别监测点超出许可取水量较多,75%的监测点从春季到冬季日取水量变化为先增后减的抛物线趋势.     

江苏省星级酒店空间布局研究

依据江苏省旅游统计数据,运用ArcGIS 9.3工具,从点和面2个层面对江苏省各星级酒店及其整体的空间布局特征进行了分析,具体采用核密度指数、莫兰I指数、吉瑞C指数和Gi指数指标.结果表明:星级酒店在江苏省内空间分布极不均衡,且各星级酒店分布差异较大;总体呈现出以苏州、南京为2个核心,由苏北到苏南逐渐集聚的态势;苏南大部分发达县市及苏中、苏北各市的市区均为星级酒店分布热点区,苏北大部分县市尤其是省界边缘及沿海地带多为冷点区.最后,分析了旅游资源和区域经济及旅游业发展水平、重要交通基础设施、政府决策行为等因素对星级酒店空间布局的影响.     

轨道交通建设对金华城镇可达性格局的影响

为了定量分析轨道交通建设对金华城镇可达性的影响,首先基于金华市公路路网结构和最短时间路径选择算法,运用Arc GIS 9.3软件对轨道交通建设前后的城镇可达性进行了对比分析.结果表明:金华各城镇的整体可达性较好,其中87%以上的区域可达性在1 h以内,并随着轨道交通建设而均得到不同程度的优化;可达性分散图在地域分布上呈现以城镇为中心的圈层分布结构;可达性较好的区域主要分布在"兰溪—金华市区—武义—永康"和"浦江—义乌—东阳—磐安"这2条轴线上,而2条轴线间城镇横向间的区域可达性较差,而且并未随着轨道交通的建设而得到明显改善;此外,因轨道交通线未贯穿磐安县,因而无论其县域内还是与其他县市间区域的可达性几乎没有发生变化.最后在上述分析的基础上,提出相应的优化措施.     

受热弹性地基梁在机械荷载作用下的非线性分析

基于弹性地基梁在均匀升温及横向均布荷载联合作用下的非线性常微分控制方程。考虑一端固定夹紧、一端可移简支边界条件,采用打靶法得到了该两点边值问题的数值结果。分析了不同参数对结构平衡路径及内力分布的影响。     

A model-based calibration method of automotive electronic control unit

This paper presents a systematic method of designing the calibration toolbox of automotive electronic control unit (ECU) based on real-time workshop (RTW). To break the strong coupling of each functional layer, the hierarchical architecture of the calibration system is divided into the bottom driver layer, the intermediate interface layer and the top application layer. The driver functions meeting the specification of the automotive open system are sent and received in the intermediate interface layer. To reduce the development costs, the portable user codes are generated by RTW which provides a development environment from system simulation to hardware implementation. Specifically, the calibration codes yielded from the controller area network (CAN) calibration protocol (CCP) module are integrated into the control codes, called by a compiler in the daemons to build a corresponding project, and then downloaded into the object board to provide the A2L file. The experiments illustrate that the different drive modules are only needed to be replaced for the implementation of the calibration system applied in different hardware platforms.     

薄互层页岩油核磁共振测井响应特征——以准噶尔盆地二叠系风城组为例

为明确核磁共振(nuclear magnetic resonance, NMR)测井仪纵向分辨率对薄互层陆相页岩响应特征的影响,以准噶尔盆地二叠系风城组3组薄互层接触面全直径岩心为研究对象,通过设计不同岩心取样方式,模拟核磁共振仪器不同纵向分辨对薄互层的核磁共振测量。研究核磁共振仪器纵向分辨率在不同薄互层厚度情况下横向弛豫时间T₂谱的响应特征的差异,明确核磁共振仪器纵向分辨率对T₂谱形态、核磁孔隙度、核磁T₂特征截止值及几何平均值的影响。结果表明：当薄互层物性差别较大且仪器纵向分辨率较低时,T₂谱形态不能准确反映真实储层特征,进行核磁测井资料解释需要考虑分辨率的影响;核磁孔隙度受仪器纵向分辨率影响较小,是薄互层探测区域的线性平均值;T₂特征截止值和几何均值会受到较大影响,会造成核磁有效孔隙度、可动流体饱和度和核磁渗透率偏小。研究结果对薄互层型页岩储层核磁共振测井评价具有重要指导意义,为核磁共振测井在页岩薄互层储层性质评价提供了参考依据。