考虑中断的制造型供应链协调调度模型

供应链协调调度能有效提高企业应对供应链中断的能力。以两阶段制造供应链为研究对象，研究了中断情境下具有交付时间约束的多产品类型制造供应链协调调度问题。制造商接到包含多产品类型的工件加工订单，各工件需经供应商处理为原材料工件后，交付给制造商处理为完成品，各工件均有一个独立的交付期。如果供应商单方面调整工件加工顺序，会导致制造商冲突成本的增加，需双方协商处理。以最小化供应商总拖期交付成本和最小化制造商总冲突成本为目标，基于收益共享契约协调机制，构建了考虑中断的制造型供应链协调调度模型。设计了一个融合自适应邻域搜索算子的混合自适应遗传算法。通过算例仿真，验证了所提模型与算法的有效性。     

基于自适应形态学的跳频信号参数联合盲估计

跳频通信的应用大大提高了军事装备的抗干扰和抗截获能力，使得跳频对抗技术面临严峻的挑战。为解决传统形态学跳频信号参数估计方法中结构元素选择困难问题并提高估计精度，提出了一种基于自适应形态学的跳频信号参数联合盲估计方法。首先，对跳频信号进行短时傅里叶变换获取谱图。然后，从其时间轴投影中获取结构元素尺寸的知识, 设计自适应形态学滤波器抑制谱图噪声, 提取跳频图案初步估计跳频参数。最后, 引入最小二乘估计方法, 对跳频周期和跳变时刻进行精估计。仿真结果表明，此方法能够同时估计出跳频频率、跳频周期和跳变时刻, 不需要其中某一种参数作为先验条件, 在复杂的通信环境也能够保持良好的估计性能。     

Dielectric relaxation and conduction mechanism in Aurivillius ceramic Bi5Ti3FeO15

For this study, we synthesized Aurivillius Bi5Ti3FeO15 ceramic using the generic solid-state reaction route and then performed room-temperature X-ray diffraction to confirm that the compound had a single phase with no impurities. The surface morphology of the prepared sample was observed to contain microstructural grains approximately 0.2–2 μm in size. The dielectric properties of the sample were determ-ined as a function of frequency in a range of approximately 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). Nyquist plots of the impedance data were found to exhibit a semi-circular arc in the high-temperature region, which is explained by the equivalent electrical circuit (R1C1)(R2QC2), where R1 and R2 represent the resistances associated with the grains and grain boundaries, respectively, C1 and C2 are the re-spective capacitances, and Q is the constant phase element (CPE), which accounts for non-Debye type of behavior. Our results indicate that both the resistance and capacitance of the grain boundaries are more prominent than those of the grains. The alternating current (ac) conductiv-ity data were analyzed based on the Jonscher universal power law, which indicated that the conduction process is dominated by the hopping mechanism. The calculated activation energies of the relaxation and conduction processes were very similar (0.32 to 0.53 eV), from which we conclude that the same type of charge carriers are involved in both processes.     

祁连山玉石沟橄榄岩中非生物成因甲烷‒石墨流体包裹体及其形成条件

研究北祁连造山带玉石沟橄榄岩中富甲烷流体包裹体。激光拉曼光谱原位分析结果显示, 这些流体包裹体主要由液态或气态 CH₄+C(石墨)组成, 次要成分为N₂, H₂O, C₂H₆和C₃H₈, 代表还原性的C-H流体形式。根据石墨的拉曼特征谱峰, 利用石墨化碳质拉曼光谱(RSCM)温度计计算石墨形成温度, 结果指示石墨在流体中沉淀的最低温度介于430~590°C之间, 表明CH₄+C是非生物成因的, 并形成于地幔环境。     

Effect of Co substitution on the structural,dielectric and optical properties of KBiFe2O5

Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample.     

吡喃葡萄糖基咪唑啉盐表面活性剂的波谱学数据分析

以1-(2,6-二甲基苯基)-1H-咪唑与2-溴乙基葡萄糖苷为原料,一步合成了新化合物溴化1-(2,6-二甲基苯基)-3-[2-(2,3,4,6-四-O-乙酰基-β-D-吡喃葡萄糖基氧基)-乙基]-咪唑盐(化合物1),是一种咪唑啉盐表面活性剂。化合物1的结构中存在糖基,含有多个手性碳原子,导致其核磁共振氢谱和碳谱较为复杂。我们运用液相色谱-高分辨质谱(LC-HRMS)和元素分析(EA)确定了其化学组成,随后通过液体核磁共振波谱技术(包括1D和2D核磁共振手段,如~1H NMR、~(13)C NMR、DEPT90、DEPT135、~1H-~1H COSY、~1H-~(13)C HSQC、~1H-~(13)C HMBC)对化合物1的氢谱和碳谱信号进行了表征,通过解析对其结构进行了详尽归属。     

不同表面活性剂对CoSb_3纳米粉体的影响及其非晶化研究

分别选用不同的表面活性剂(SDBS、CTAB、EDTA、PVP),采用水热法成功制备CoSb_3纳米粉体.对制备的纳米粉体分别进行XRD和SEM表征,研究了不同表面活性剂对制备的CoSb_3纳米粉体的影响.结果表明不同表面活性剂对制备的CoSb_3纳米粉体形貌有显著的影响.并将水热法制备的CoSb_3纳米粉体,采用脉冲激光非晶化技术进行处理,结果表明纳米粉体实现了部分非晶化.通过样品的XRD分析研究了影响CoSb_3纳米粉体部分非晶化的条件,结果表明扫描重复次数的增加可以提高CoSb_3基方钴矿热电材料的非晶化能力,适当提高扫描速度有利于CoSb_3基方钴矿热电材料的非晶化.     

基于R语言的迪基-福勒检验的蒙特卡罗模拟

迪基-福勒(Dickey-Fuller)检验是时间序列的平稳性检验中常用的一种方法;由于检验统计量的极限分布是由标准维纳过程关于轨道的积分来表达的,很难得到其密度函数的显式表达式,因而确定检验临界值非常困难,蒙特卡罗方法是解决这类问题的金钥匙;基于R语言对t统计量的平稳性检验的临界值的随机模拟程序进行了研究,填补了文献空白,其计算程序和方法对于金融工程或经济计量统计分析与研究具有广泛的指导意义。     

时间尺度上奇异变质量可控非完整系统的Noether对称性

研究时间尺度上奇异变质量可控非完整系统的Noether对称性与守恒量.首先以时间尺度上的Hamilton原理为基础，建立时间尺度上奇异变质量可控非完整系统的运动方程，然后依据Hamilton作用量在无限小变换下的不变性，给出该系统Noether广义准对称性的判据和Noether广义准对称性所对应的守恒量，最后举例说明研究结果的应用.     

不同阶次下分数阶SIR传染病模型的稳定性分析

建立一类考虑Logistic增长与饱和传染率的不同阶次分数阶时滞传染病模型. 首先, 利用Jacobi矩阵和特征根轨迹法, 分析该模型的局部稳定性, 并给出基本再生数; 其次, 选取分岔参数作为时滞, 给出地方病平衡点发生Hopf分岔的充分条件； 最后, 利用数值仿真验证理论分析的正确性. 研究结果表明, 分数阶次的改变会影响系统的稳定性.