金具零部件表面防腐蚀试验研究

随着经济的持续高速增长，各行业用电需求增大。在加快特高压骨干电网建设的同时，提高现有电网的输电能力、输电质量成为重中之重。金具是海上换流站的重要组成部分，海洋环境的特殊性，对金具提出了更高的耐腐蚀性能要求。为了探究海洋环境对金具的腐蚀性，选用ZL101A和ZL102两种典型的铝合金金具，采用5种辅助防腐蚀工艺获得5种耐腐蚀样本，并模拟海上工况对其分别进行盐雾腐蚀试验，得出最优防腐蚀工艺。研究表明：ZL101A和ZL102两种铝合金具有一定的耐腐蚀性能，ZL101A铝合金的耐腐蚀性能强于ZL102铝合金的；抛丸处理的防腐措施在ZL101A铝合金样本中的防腐蚀表现要强于ZL102铝合金样本的；阳极氧化在两种材质中防腐蚀表现均为优异，是最优异的防腐蚀工艺。     

Effect of heat treatment on microstructures and properties of a novel Al-Zn-Mg-Cu alloy for oil drilling

In view of the special requirements for strength, heat resistance and corrosion resistance of Al-Zn-Mg-Cu alloy for oil drilling, the Al-6.2 Zn-2.5 Mg-1.6 Cu alloy was prepared by increasing Cu content on basis of Russian Series 1953 alloy. The effect of heat treatment on the microstructures and properties of the alloy was characterized by optical microscope(OM), scanning electron microscope(SEM) and transmission electron microscope(TEM), and investigated by tensile test at room temperature, thermal exposure test and corrosion test. The results show that the strength after T6 aging treatment exhibit a decrease trend as an increase of the solution temperature from465 °C to 480 °C. After the solution treated by the rate of 470 °C/1 h, second phases dissolve into the matrix very well and the strength property reaches optimum. The alloy has better comprehensive properties treated by a solution treatment of 470 °C/1 h and then followed by an aging treatment of 120 °C/24 h + 170 °C/1 h + 120 °C/24 h. Under the aging state, the precipitated phases inside the grains are suitable in size, while on the grain boundary distribute discontinuously and the precipitate-free zone is obvious. Besides, the alloy still maintain high tensile properties. The yield strength, tensile strength and elongation are 650 MPa, 686 MPa,12.0%, respectively. The yield strength retention after heat exposure is 92%. The alloy has good corrosion resistance and the exfoliation corrosion degree. The average corrosion rate in the H_2S and CO_2 environment is 0.0024 mm/a, which is far less than the required 0.12 mm/a. It is insensitive to H_2S and CO_2 environments.     

斜坡桩-土体系动力p-y曲线影响因素分析

碎石土斜坡场地桩-土体系动力相互关系及其主要影响因素的研究成果鲜少。基于此，本文以西南地区穿越典型地形地貌和地基土大类的某一线路工程为例，调研分析斜坡桩基震害特点，并采用FLAD3D建立斜坡桩-土体系分析模型，研究斜坡桩-土体系动力p-y曲线的影响因素。获得了动力荷载作用下碎石土斜坡动力p-y曲线基本特点，建议了以滞回圈极值点或拐点绘制骨干曲线的方法，进一步归结出动力p-y曲线的刚度、桩土相互作用力、桩土相对位移及曲线滞回圈面积与埋深、桩径、碎石土相对密度和斜坡坡度的关系，最终引入桩侧土反力的桩径影响因子FD、土性密度影响因子FM、斜坡坡度影响因子Fβ，用于描述上述因素对桩侧土反力影响情况。以上研究成果可以更好的表述碎石土斜坡桩基在地震荷载作用下的桩-土体系间相互关系。     

Superior corrosion resistance-dependent laser energy density in(CoCrFeNi)95Nb5 high entropy alloy coating fabricated by laser cladding

(CoCrFeNi)95Nb5 high entropy alloy(HEA)coatings were successfully fabricated on a substrate of Q235 steel by laser cladding technology.These(CoCrFeNi)95Nb5 HEA coatings possess excellent properties,particularly corrosion resistance,which is clearly superior to that of some typical bulk HEA and common engineering alloys.In order to obtain appropriate laser cladding preparation process parameters,the effects of laser energy density on the microstructure,microhardness,and corrosion resistance of(CoCrFeNi)95Nb5 HEA coating were closely studied.Results showed that as the laser energy density increases,precipitation of the Laves phase in(CoCrFeNi)95Nb5 HEA coating gradually decreases,and diffusion of the Fe element in the substrate intensifies,affecting the integrity of the(CoCrFeNi)95Nb5 HEA.This decreases the microhardness of(CoCrFeNi)95Nb5 HEA coatings.Moreover,the relative content of Cr2O3,Cr(OH)3,and Nb2O5 in the surface passive film of the coating decreases with increasing energy density,causing corrosion resistance to decrease.This study demonstrates the controllability of a high-performance HEA coating using laser cladding technology,which has significance for the laser cladding preparation of other CoCrFeNi-system HEA coatings.     

原位生成NbC增强YCF102熔覆层热力学与耐磨性研究

熔覆层性能难以满足特定的工艺要求，已成为限制激光熔覆发展的关键因素之一.鉴于此，在45号钢基体上制备出原位生成NbC增强YCF102熔覆层，并进行了热力学分析.通过XRD，SEM和EDS对其微观形貌及组成成分进行了分析，对其显微硬度及耐磨性进行了研究.结果表明:激光功率的改变对激光熔覆过程中原位反应的反应程度有显著影响，过大或者过小的激光功率均会对原位反应的发生起到抑制作用;YCF102熔覆层中原位生成的NbC颗粒的主要形态为四边形和花瓣形;当激光功率为525W时，原位生成NbC增强YCF102熔覆层具有较高的显微硬度及良好的耐磨性.     

Mechanical behavior of a near α titanium alloy under dynamic compression: Characterization and modeling

Dynamic compression tests under strain rates from 870 s^?1 to 2100 s^?1 were conducted for a near α Ti–8Al–1Mo–1V titanium alloy with equiaxed microstructure. Compression behavior, adiabatic shearing and band microstructure were investigated via characterization and calculation. The results demonstrate that all dynamic constitutive curves exhibited obvious stress fluctuation phenomenon with double increase-decrease changing stages at the primary stage of compression. The dislocation multiplication theory can be used to explain this phenomenon. After the stress fluctuation period, work hardening coexisted with the thermal softening, resulting in the slow hardening tendency in constitutive curves. J-C model was utilized to quantify the dynamic constitutive curves. The deviations between the predicted and experimental curves under high strain rates may be attributed to the over-consideration of thermal softening effect in J-C model. Adiabatic shearing band (ASB) began to form under the strain rate of 2100 s^?1. A total shearing strain of 8.1 within ASB achieved in 8.9 μs, corresponding to a local strain rate of about 9.1 × 10⁵ s^?1 and is over 430 times of the macro strain rate. Post annealing was conducted on ASB before EBSD characterization. Due to the static recrystallization during annealing, the α phase within ASB generally presented as ultra-fine grains less than 1 μm in diameter.     

南水北调中线工程水源区抗生素抗性基因多样性研究

为了研究丹江口水库和汉江抗生素抗性基因(Antibiotic Resistance Genes, ARGs)的污染现状与分布规律, 采用高通量测序的方法, 于2014年春季和秋季分别对丹江口水库及汉江沿程的ARGs多样性进行检测。分别在春秋两季样本中检测出21和19类ARGs, 其中9类ARGs是水体ARGs的主要组成部分。杆菌肽类ARGs是水体中最主要的ARGs, 而β-内酰胺类ARGs在春季丹江口水库陶岔采样点中占比最高。秋季水体各采样点的ARGs组成结构差异比春季小, 通过NMDS和ANOSIM分析发现ARGs的组成存在显著的季节差异, 甲氧苄氨嘧啶类、多粘菌素类和多重耐药类ARGs是具有显著季节差异的ARGs种类。由相关性分析发现13类具有互相显著强相关关系的ARGs, 其中相关性最强的ARGs很可能共存于一种微生物中。此外, 四环素类和氨基糖苷类ARGs可能作为预测水源区中与其共存ARGs相对丰度的指示种类。研究结果可为饮用水源区的水质保护和ARGs 污染防治与管理提供科学依据。     

取用水监测点的水量计算与变化趋势分析

加强取用水监测是实施最严格水资源管理制度的重要举措.为了更有效地利用大量的取用水在线监测数据,需要对获取的监测数据进行预处理.本文首先提出应用中位数法与曲线拟合相结合的方法对取用水监测数据进行异常值检测,再用曲线拟合方法对异常值进行校正;其次,根据校正后得到的数据进行两个方面的分析,一方面是计算监测点的年取水量,另一方面是应用集成经验模态分解方法分析监测点的日取水量变化趋势;最后,以M市的16个自来水厂2016年取用水在线监测数据为例进行实证分析,结果表明,本文提出的中位数法与曲线拟合相结合的方法能够有效地检测异常值,进而再用曲线拟合方法能够更好地对异常值校正.根据校正后得到的数据进行分析发现81%的监测点年取水量相对2011年水利普查数据有所增加,个别监测点超出许可取水量较多,75%的监测点从春季到冬季日取水量变化为先增后减的抛物线趋势.     

气膜条件下车厢表面摩擦阻力计算理论研究

针对气膜条件下厢式运输车厢体表面摩擦阻力减小的实验结果,分别提出边界层加厚理论、混合降速理论、边界层加厚-混合降速理论3种理论来研究空气介质中空气膜的减阻机理,建立了气膜条件下厢式运输车厢体表面气流摩擦阻力计算模型,定性对比分析了厢体表面在有气膜和无气膜条件下各自所受到的气流摩擦阻力.结果表明,有气膜时摩擦阻力减小,这一结果与笔者前期的实验研究结果趋于一致,为气膜减阻在厢体表面减阻中的实际应用提供了理论基础.     

高速公路出行距离特征分析与应用

为分析高速公路出行距离特征与快速准确地计算高速公路起讫点(origin-destination,OD)矩阵,通过统计收费数据探寻不同车型的出行距离特征,并结合收费站点区域的联系强度构建OD估算模型。根据车型分类标准对收费数据进行分车型整合处理,利用频数分析和曲线拟合建立出行特征函数,并利用空模型法模拟客车和货车距离衰减规律;根据收费站不同行车区间内出行概率与节点间的联系强度,建立基于驾驶员出行特征的OD估算模型并进行实例分析。结果显示:河北省客、货车出行距离区间分别集中在50～150 km与100～300 km;距离衰减系数分别为1.08和1.205,不同于默认值2,随距离的增加有显著的衰减趋势;客车和货车最佳拟合函数分别为对数正态分布和正态分布,OD估算结果误差小于5%。