316奥氏体不锈钢渗N/镀CrN复合改性层组织与性能

分别在400、440、480 ℃下对316奥氏体不锈钢进行12 h的渗氮处理,再对渗氮后的试样进行物理气相沉积(PVD)镀CrN薄膜.采用扫描电镜(SEM)、光学显微镜(OM)、X射线衍射仪(XRD)、维氏显微硬度计和材料表面综合测试仪(HSR-2M)、电化学工作站等对复合改性层的表面形貌、截面形貌、成分、显微硬度、耐磨性以及耐蚀性进行测试.结果表明:400 ℃离子渗N/镀CrN试样耐磨性最差,耐蚀性最好;而480 ℃离子渗N/镀CrN试样耐磨性最好,耐蚀性最差;但比相同温度下单独渗氮试样的综合性能好.     

45~#钢微孔陶瓷化及其摩擦磨损性能研究

金属的软氮化是金属表面强化的一种化学热处理方法,通过加热试样到实验所需的温度时进行适当的保温,使氮离子、碳离子渗入到金属的表面。通过干滑动摩擦试验方法,对在不同渗氮温度和渗氮时间条件下45#钢进行摩擦磨损试验,得出了硬度变化曲线和摩擦系数变化曲线,对比分析了各种条件下的磨损量,并与未处理试样进行比较分析。结果表明,渗氮处理的45#钢比未处理的45#钢具有较强的硬度和耐磨性,而且随着渗氮时间的增加和渗氮温度的升高,45#钢的耐磨性和硬度都有所增加,摩擦系数则有所减小。     

低温盐浴渗氮对Custom 465钢耐蚀及耐磨性的影响

为了提高Custom 465马氏体沉淀硬化不锈钢的耐磨性,分别在440、480和520℃对580℃时效后的样品进行了2 h的盐浴渗氮,使用显微硬度计、X射线衍射仪、电化学工作站、球盘式摩擦磨损仪、表面轮廓仪、扫描电镜等设备,研究渗氮温度对Custom 465钢表面物相、硬度、渗层显微形貌、耐蚀性及耐磨性的影响. 随着渗氮温度升高,耐蚀性逐渐降低,但表面硬度增加,520℃处理后表面硬度增大到1240 HV,较未处理试样的400 HV明显上升,渗层厚度达到22μm. 440℃渗氮后表面物相为氮在马氏体基体中过饱和的α'N ,点蚀电位降低约60 mV;480℃时有少量CrN相析出,引起点蚀电位降低约180 mV,同时磨损体积下降约43%;520℃时CrN相的含量明显升高,自腐蚀电位降低约70 mV,无明显的稳态钝化区,磨损体积降低82%,减磨效果明显.     

Experimental and numerical study on plasma nitriding of AISI P20 mold steel

In this study, plasma nitriding was used to fabricate a hard protective layer on AISI P20 steel, at three process temperatures (450°C, 500°C, and 550°C) and over a range of time periods (2.5, 5, 7.5, and 10 h), and at a fixed gas N₂:H₂ ratio of 75vol%:25vol%. The morphology of samples was studied using optical microscopy and scanning electron microscopy, and the formed phase of each sample was determined by X-ray diffraction. The elemental depth profile was measured by energy dispersive X-ray spectroscopy, wavelength dispersive spectroscopy, and glow dispersive spectroscopy. The hardness profile of the samples was identified, and the microhardness profile from the surface to the sample center was recorded. The results show that ε-nitride is the dominant species after carrying out plasma nitriding in all strategies and that the plasma nitriding process improves the hardness up to more than three times. It is found that as the time and temperature of the process increase, the hardness and hardness depth of the diffusion zone considerably increase. Furthermore, artificial neural networks were used to predict the effects of operational parameters on the mechanical properties of plastic mold steel. The plasma temperature, running time of imposition, and target distance to the sample surface were all used as network inputs; Vickers hardness measurements were given as the output of the model. The model accurately reproduced the experimental outcomes under different operational conditions; therefore, it can be used in the effective simulation of the plasma nitriding process in AISI P20 steel.     

用表面裂纹法研究表面强化层的疲劳裂纹扩展抗力

本文采用表面裂纹法研究了碳氮共渗、氮化及滚压强化层的疲劳裂纹扩展抗力。与常规的紧凑拉伸试验法相比，前者能灵敏地反映出表面强化层组织及性能的影响，后者却难于实现。试验证实碳氮共渗层中由于残留奥氏体应变诱发马氏体，导致疲劳裂纹扩展抗力提高；滚压强化及渗氮均能提高表面压应力，也使疲劳裂纹扩展抗力明显提高。     

氮化40Cr制作潜水泵主轴的研究

研究了40Cr钢经辉光离子氮化处理取代3Cr13钢制作潜水泵轴的可行性。讨论了氮化对40Cr钢组织、耐磨性、耐蚀性及变形的影响。结果表明:40Cr钢经辉光离子氮化处理后,与3Cr13钢相比,具有优良的耐磨性、耐蚀性和尺寸稳定性。采用此种工艺制作潜水泵轴,性能上符合要求,而且成本低,具有明显的经济效益。     

Fe-0.64at％Ti二元合金系统低温氮化内耗峰谱的研究

系统地测量了400℃氯化的Fe-0.64Ti合金系统不同热处理制度下异常内耗峰的行为.提出了230℃峰的Ti-N_2仨缺陷模型,指出了100—150℃峰与高温时效过程中在{100}_α面上形成富钛、氮的预沉淀相紧密相关.     

纯铁氮化层时效的透射电镜研究

用透射电镜研究了纯铁离子氮化缓冷后时效时,其扩散层中相的转变过程,并用实验力学中测定宏观应变的Moire法原理,通过对电镜水纹图象进行分析,测定了a"与a_N相间的共格应变值。     

42CrMo钢离子氮化—沉淀强化组织结构的研究

研究了42CrMo钢离子氮化—沉淀强化的组织结构,结果表明,离子氮化层的组成为ε、r＇a_N、Fe_3C和少量Cr_2N、Mo_2N、CrMoN_x及a";经时效处理后,ε相和a_N相弥散析出Cr_2N、Mo_2N和a" 。325℃时效,CrMoN_x消失;500℃时效,Mo_2N大大减少。a"、Cr_2N和Mo_2N弥散共格析出,必将使氮化层强化。