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1.
二硫化钼是类似于石墨烯的二维层状材料,其优异的磁学性能、电学性能、催化性能和光学性能受到了科研人员的广泛关注.通过水热法制备出4种不同形貌的二硫化钼纳米片.对二硫化钼样品进行扫描电子显微镜测试,以200 W钨丝灯为光源,在暗箱中进行甲基橙溶液的降解测试.通过紫外可见光分光光度计对测试样品溶液进行吸光度测试,得出纳米片状的二硫化钼光催化降解甲基橙溶液降解率最高.  相似文献   
2.
为了解决传统求解非线性波物相互作用计算量大和精度低的问题,采用时域二阶势流理论方法,对三维非波物相互作用问题进行研究.自由表面边界条件考虑到二阶边界值问题并采用IFBC(积分格式的自由面条件)来更新自由面上的速度势;在水底基于镜像的原理对格林函数进行修正;在远方辐射边界上采用水波透射器来外传绕射波;控制方程的离散求解是使用无奇异边界元方法来计算每个时间步上的流场分布.基于上述模型,对直立圆柱的二阶绕射问题进行了研究,得出的各阶力与解析解在低频和高频部分都符合得较好,可以用于分析类似非线性波物相互作用问题.  相似文献   
3.
针对现阶段微观剩余油研究中可视化精度低、微观剩余油与矿物之间的依存关系不明确以及形态分类描述不完善等问题, 利用岩芯观察、铸体薄片分析、X射线衍射分析等手段, 以场发射环境扫描电子显微镜(FE-SEM)图像为基础资料, 联合能谱(EDS)分析资料, 研究鄂尔多斯盆地中部长2油层组和长9油层组的微观剩余油分布规律, 并探讨剩余油赋存状态的矿物学机制。结果表明, 微观剩余油的赋存状态由孔隙的大小和形态以及与孔隙相接触的边缘矿物的性质共同决定, 不同类型孔隙对剩余油的赋存能力取决于孔隙边缘矿物的形态、表面粗糙程度、比重和润湿性等物理化学性质。据此, 可将微观剩余油分为残留油团、半自由油岛、半自由油雾、半自由微油团和束缚油5个类型。  相似文献   
4.
基于k-ε湍流模型,在STAR-CCM+平台上建立数值波浪水池,开发透水式多层开孔板消波装置并研究其消波特性.波浪水池利用流体体积(Volume of Fluid, VOF)方法追踪自由液面,采用STAR-CCM+的VOF WAVE模块造波,出口边界设置阻尼消波区.通过对一系列指定波浪的模拟,验证了数值水池的准确性.改变波长、波高、水流的流速和方向,可得到消波装置在不同波流条件下的反射与透射系数.结果表明:反射系数和透射系数均随波长增加而增大;反射系数随波高增加而增大,透射系数随波高增加而减小;波流共同作用工况下,反射系数和透射系数远小于波浪单独作用工况;在模拟波流条件下,所开发的消波装置消波性能显著.  相似文献   
5.
超表面是具有亚波长尺度周期性人造结构的一种二维超材料,通过结构设计,对入射电磁波进行控制,在各类器件上有非常广泛的应用前景.石墨烯具有独特的电学、光学、热学和机械特性,石墨烯超表面受到了越来越多的关注.利用外部电压改变石墨烯的电导率可以灵活地设计出不同功能的器件.介绍了超表面的基本概念,根据超表面的分类简述了各类石墨烯超表面的发展进程,并对目前问题和未来发展趋势进行了讨论.  相似文献   
6.
In this work, different effects of substrates on the morphologies of single-walled carbon nanotubes (SWNTs) are studied. SWNTs were produced by floating catalytic chemical vapor deposition using CH4 as carbon source gas and Ar as carrier gas. Then the SWNTs were deposited on lithography-patterned different substrates. The as-grown SWNTs at the boundaries between SiO2 and metal were characterized by scanning electron microscopy, atomic force spectroscopy and Raman spectroscopy. It is found that SWNTs deposited on low-conductivity substrates trend to have curved morphologies and some of them form rings, while SWNTs deposited on metal sub- strates remain straight and orientated. The mechanism of these effects was also discussed, which is closely related to the thermal conductivities and the principle of energy dissipation.  相似文献   
7.
An Al-Mg-Si-Cu-Fe alloy was solid-solution treated at 560℃ for 3 h and then cooled by water quenching or furnace cooling. The alloy samples which underwent cooling by these two methods were rolled at different temperatures. The microstructure and mechanical properties of the rolled alloys were investigated by optical microscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction analysis, and tensile testing. For the water-quenched alloys, the peak tensile strength and elongation occurred at a rolling temperature of 180℃. For the furnace-cooled alloys, the tensile strength decreased initially, until the rolling temperature of 420℃, and then increased;the elongation increased consistently with increasing rolling temperature. The effects of grain boundary hardening and dislocation hardening on the mechanical properties of these rolled alloys decreased with increases in rolling temperature. The mechanical properties of the 180℃ rolling water-quenched alloy were also improved by the presence ofβ″phase. Above 420℃, the effect of solid-solution hardening on the mechanical properties of the rolled alloys increased with increases in rolling temperature.  相似文献   
8.
提出一种计算粗糙海面条件下空气中声源激发水下声场的方法,并通过数值仿真研究粗糙海面对水下声场的影响.在波数积分模型的基础上,采用微扰法将声场分为平均声场和散射声场之和.其中,平均声场采用国际流行的波数积分模型OAST计算,散射声场采用自相容扰动法计算.对不同风速、不同声源频率条件下的声场进行仿真,结果表明风速越大、声源频率越高,总声压变化范围越大,同时,水下接收到的平均声压和均方声压受到的影响越大.  相似文献   
9.
A novel glucose biosensor based on graphene nanosheets (GNs) modified gold nanowire arrays (AuN- WAs) electrode was constructed. Highly ordered gold nanowire arrays were prepared by direct electrodeposition in anodic aluminum oxide templates. GNs were synthe- sized through a public route involving graphite oxidation, exfoliation, and chemical reduction. Field emission scan- ning electron microscope and high-resolution transmission electron microscope were employed to characterize the as- prepared AuNWAs and GNs. Glucose oxidase was immobilized on the surface of GNs-AuNWAs modified electrode via a cross-linking method. The cyclic voltam- metry results showed that the GNs-AuNWAs-based glu- cose biosensors have high catalysis activity to hydrogen peroxide (H2O2) than those modified with GNs or AuN- WAs only. Furthermore, amperometric response was employed to detect glucose concentration owing to its simplicity, high selectivity, and relative low cost. Glucose biosensors based on GNs-AuNWAs showed excellent performance with high sen- sitivity of 40.25 μA cm^-2 (mmol/L)^-1, low detection limit of 0.02 mmol/L, and a linear range from 0.02 to 3 mmol/L.  相似文献   
10.
Fe5O7(OH)·4H2O ferrihydrite is a low-crystal- linity antiferromagnetic material, γ-Fe2O3 (maghemite) magnetic nanoparticles were prepared from a ferrihydrite precursor, by chemically induced transformation in FeCl2/ NaOH solution. The magnetization, morphology, crystal structure and chemical composition of the products were determined by vibrating sample magnetometry, transmission electron microscopy, X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy (XPS). Ferrihydrite underwent aggregation growth and transformed into α-FeO(OH) (goethite) particles, which subsequently transformed into γ-Fe2O3 nanoparticles, that became coated with NaCI. The γ-Fe2O3 particles had a flake-like morphology, when prepared from 0.01 mol/L FeCl2 and a FeCl2:NaOH molar ratio of 0.4. The γ-Fe2O3 particles were more spherical, when prepared from a FeCl2:NaOH molar ratio of 0.6. The Fe content of the flake-like particles was lower than that of the spherical particles. Their magnetizations were similar, and the coercivity of the flake-like particles was larger. The differences in morphology and magnetization were attributed to the surface effect, and the difference in coercivity to the shape effect.  相似文献   
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