磨粒和抛光垫对铝合金化学机械抛光性能

磨粒和抛光垫为化学机械抛光(CMP)提供了重要的机械磨削作用。为了探讨磨粒和抛光垫对铝合金化学机械抛光的磨削作用,研究了不同种类磨粒和抛光垫对材料去除率和表面形貌的影响。结果表明：在pH=12-13时,氧化铝抛光液去除率(MRR)为910nm/min,远大于二氧化硅与氧化铈抛光液,且获得较为理想光滑表面。3种不同抛光垫抛光后的铝合金表面,呢子抛光垫表面将不会出现划痕与腐蚀点,表面粗糙度较低为10.9nm。随着氧化铝浓度的增加,材料去除率(MRR)和表面粗糙度(Ra)均增加。当氧化铝含量为4wt%时,抛光垫使用呢子抛光垫适宜铝合金化学机械抛光,在获得高去除率的同时铝合金表面精度高。     

M（CH3 OH）1~4（M=Be2+/Mg2+/Ca2+）团簇的量子化学研究

应用量子化学方法 B3LYP/6-311+G(d,p),对气相团簇M(CH3OH)1~4(M=Be2+/Mg2+/Ca2+)的结构、能量进行计算,采用HF/STO-3G方法对电荷分布进行研究.结果表明,甲醇分子通过O原子配位于金属离子形成最稳定结构,金属与CH3OH中的O的距离由大到小为RCa-ORMg-ORBe-O,而结合能由大到小依次为Be2+Mg2+Ca2+.随着甲醇分子数n的增加,金属离子与O的距离RM-O逐渐增大,总结合能逐渐增大,连续结合能逐渐减小,金属离子所带的正电荷在逐渐减小,对于相同配位数n,Be2+的电荷转移量最大,Ca2+的电荷转移量最小;甲醇分子中各原子所得正电荷的大小顺序为H(-HO)H(-H3C)CO.     

Ni基合金激光熔覆层裂纹机理研究

激光熔覆得到的Ni基合金熔覆层容易出现裂纹,这是导致Ni基合金熔覆层失败的主要因素.基于实验及微观检测分析,以Ni60熔覆层为研究对象,从组织和应力方面对激光熔覆过程中熔覆层裂纹的开裂及扩展机理进行了研究.综合熔覆层微观组织、物相以及断口形貌分析发现,熔覆层不同位置晶体组织差异显著,材料硬度与裂纹敏感性随硬质相分布的增加而升高,Ni60熔覆层的裂纹属于准解理的脆性断裂,裂纹萌生于熔覆层顶部,并沿硬质相向内部规律性扩展.根据热残余应力模型与Griffith脆性断裂强度模型建立了涂层开裂判据,并在此基础上提出相应的裂纹消除方法,改善了金属的性能.     

Products Ranking Through Aspect-Based Sentiment Analysis of Online Heterogeneous Reviews

With the rapid growth of online shopping platforms, more and more customers intend to share their shopping experience and product reviews on the Internet. Both large quantity and various forms of online reviews bring difficulties for potential consumers to summary all the heterogenous reviews for reference. This paper proposes a new ranking method through online reviews based on different aspects of the alternative products, which combines both objective and subjective sentiment values. Firstly, weights of these aspects are determined with LDA topic model to calculate the objective sentiment value of the product. During this process, the realistic meaning of each aspect is also summarized. Then, consumers’ personalized preferences are taken into consideration while calculating total scores of alternative products. Meanwhile, comparative superiority between every two products also contributes to their final scores. Therefore, a directed graph model is constructed and the final score of each product is computed by improved PageRank algorithm. Finally, a case study is given to illustrate the feasibility and effectiveness of the proposed method. The result demonstrates that while considering only objective sentiment values of the product, the ranking result obtained by our proposed method has a strong correlation with the actual sales orders. On the other hand, if consumers express subjective preferences towards a certain aspect, the final ranking is also consistent with the actual performance of alternative products. It provides a new research idea for online customer review mining and personalized recommendation.     

聚苯胺纳米纤维的合成与分散性研究

为解决聚苯胺纳米纤维难分散的问题,引入超声波技术,采用直接混合+超声法合成聚苯胺纳米纤维;又试用新的硬模板+超声振荡法合成聚苯胺纳米纤维。通过实验现象观察、红外光谱和扫描电镜检测,获得了制备分散均匀、直径约100nm、长300nm的聚苯胺纳米纤维的工艺条件。     

灰色GM(1,1)模型在山区耕地预测中的应用研究

以云南楚雄1999-2005年耕地面积数据为试验资料,运用灰色GM(1,1)模型分析探讨耕地面积的变化状况.初步结果表明:楚雄耕地面积的动态变化结果符合客观实际的变化规律,未来几年,楚雄拼地面积仍呈递减的趋势.     

风机—液力偶合器模糊-PID调速控制系统研究

对风机—液力偶合器单一PID控制系统过度依赖控制模型问题,提出了基于PID控制的高稳定性和模糊控制的高鲁棒性的风机—液力偶合器模糊-PID控制.在分析大功率煤气风机与YOCQZ420调速型液力偶合器调速控制系统动态调节特性的基础上,推导并建立了调速控制系统的动态调节数学模型;应用计算机分析软件,在一定开关阈值和不同时间常数、系统总增益和延迟时间常数条件下的模糊-PID双模调速控制系统进行仿真分析.实验台实验测试结果与仿真分析结果的一致性表明,模糊-PID双模控制可有效实现大功率风机与调速型液力偶合器调速的自动控制.     

基于双域名双链路校园网的DNS加速分析及实施

基于VIEW和策略路由的方案在双链路或多链路校园网中的广泛应用,使公众网访问校园网时DNS解析超时的问题凸显出来.本文结合实际,针对拥有www.xxx.edu.cn和www.xxx.cn双域名的双链路校园网,提出DNS加速方案并进行原理分析及实施,对复杂结构下DNS的配置有一定的参考价值.     

变质心自旋弹头的建模及自适应滑模控制

对自旋弹头实现末端机动的变质心控制系统进行了研究.为了明确表示自旋弹头的运动参数与质量块运动参数之间的关系,采用牛顿力学方法建立自旋弹头的姿态运动模型.模型包括质量块运动方程、姿态运动的运动学方程和动力学方程.考虑到俯仰和偏航通道的动力学特性为非线性的、铰链耦合的,采用自适应滑模控制方法设计了变质心控制系统,对系统中的不确定项进行估计和补偿,保证系统的跟踪误差收敛到零.变质心控制系统通过对质量块的偏移运动进行控制,进而准确地控制自旋弹头的姿态运动.为了检验所设计的变质心控制系统的控制性能,利用MATLAB/Simulink软件构建系统的仿真模型,进行仿真研究.仿真结果表明:所设计的变质心控制系统具有较高的快速性和控制精度,实现了对自旋弹头姿态角的准确控制.     

Morphologic characteristics and growth interface stability of nano-micron FeS2 whiskers

Micromorphology is further studied on the basis of our previous researches concerned with the nano-micron FeS2 whisker. There are obvious differences in the intensive degree, diameter and micro- morphology among the FeS2 whiskers growing in different stages. From the early to late stage, the intensive degree increases, the diameter decreases, and the surface micro-morphology changes following the regularity： protrusive nodulation → coarse → smooth → flat. According to the theory of crystal growth, the geological setting and processes of whisker formation, we discuss the stability and evolution of crystal growth interface of FeS2 whisker occurring in Gengzhuang gold deposit （Shanxi Province, China）. The results suggest that the negative temperature gradient and the supercooling appear in the early stage of the whisker growth, whereas the positive temperature gradient of reposeful state appears in the late stage. In the whisker growth stage, the component concentration changes through the three stages： severely nonhomogeneous in the early stage, relatively homogeneous in the middle stage, more homogeneous in the late stage. The general changing process of the interfacial state is from unstable to stable. Micromorphology of FeS2 whisker in Gengzhuang is the result of synergism of temperature, component concentration and stability of crystal interface phase in hydrothermal system. The micromorphology not only reflects the physical and chemical characteristics of the hydrothermal system during the whisker growth, but also indicates the stability characteristics of the interface phase and records the changing process of the whisker growth.