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1.
Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample. 相似文献
2.
The effect of cold rolling and post-rolling heat treatment on the microstructural and electrochemical properties of the 316L stainless steel was investigated.Two-pass and four-pass cold-rolled stainless steel specimens were heat-treated by annealing at 900℃followed by quenching in water.During the cold rolling,the microstructure of the as-received specimen transformed from austenite to strain-inducedα′-martensite due to significant plastic deformation that also resulted in significant grain elongation(i.e.,~33%and 223%increases in the grain elongation after two and four rolling passes,respectively).The hardness of the heat-treated as-received specimen decreased from HV 190 to 146 due to the recovery and recrystallization of the austenite grain structure.The cyclic polarization scans of the as-rolled and heat-treated specimens were obtained in 0.9wt%NaCl solution.The pitting potential of the four-pass rolled specimen was significantly increased from 322.3 to 930.5 mV after post-rolling heat treatment.The beneficial effect of the heat treatment process was evident from~10-times-lower corrosion current density and two-orders-of-magnitude-lower passive current density of the heat-treated specimens compared with those of the as-rolled specimens.Similarly,appreciably lower corrosion rate(3.302×10?4mm/a)and higher pitting resistance(1115.5 mV)were exhibited by the postrolled heat-treated specimens compared with the as-rolled 316L stainless steel specimens. 相似文献
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For this study, we synthesized Aurivillius Bi5Ti3FeO15 ceramic using the generic solid-state reaction route and then performed room-temperature X-ray diffraction to confirm that the compound had a single phase with no impurities. The surface morphology of the prepared sample was observed to contain microstructural grains approximately 0.2–2 μm in size. The dielectric properties of the sample were determ-ined as a function of frequency in a range of approximately 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). Nyquist plots of the impedance data were found to exhibit a semi-circular arc in the high-temperature region, which is explained by the equivalent electrical circuit (R1C1)(R2QC2), where R1 and R2 represent the resistances associated with the grains and grain boundaries, respectively, C1 and C2 are the re-spective capacitances, and Q is the constant phase element (CPE), which accounts for non-Debye type of behavior. Our results indicate that both the resistance and capacitance of the grain boundaries are more prominent than those of the grains. The alternating current (ac) conductiv-ity data were analyzed based on the Jonscher universal power law, which indicated that the conduction process is dominated by the hopping mechanism. The calculated activation energies of the relaxation and conduction processes were very similar (0.32 to 0.53 eV), from which we conclude that the same type of charge carriers are involved in both processes. 相似文献
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结合工程实际,通过室内模型试验方法,研究锥柱式桩基础明挖基坑回填土在模拟实际环境温度条件下的回冻过程.结果表明,在模拟平均温度为-2.71℃的环境温度条件下,正温极值时刻表层土体融化深度约6.1 cm,回填土冻结深度随着冻融次数的增加而增厚,经历13次冻融循环,冻结层厚度达20.0 cm;桩基沿着水平向和纵向对回填土回冻过程产生影响,但其影响范围有限;土体和桩基与空气界面温度存在差异,桩基和空气界面处温度接近低温试验箱内空气温度,土体和空气界面处与空气温度差别较大,正温极值状态,空气温度高于土表温度5.0℃,负温极值状态,空气温度低于土表温度6.7℃.试验结果有助于进一步认识此类桩基回填土实际回冻过程,为确定模型试验控温条件及数值模拟边界条件提供参考. 相似文献
7.
为研究不同介质条件对高强度混凝土冻融损伤及抗氯盐侵蚀性的影响,分别以清水和盐水为介质,对高强混凝土试块进行了快速冻融试验。并将冻融后试块置于氯盐溶液中进行浸泡试验,比较了不同介质下高强混凝土冻融损伤形态、质量损失率和饱和吸水率等方面的差异,分析了冻融对高强混凝土氯离子分布规律和氯离子扩散系数的影响。试验结果表明,盐冻条件下高强混凝土表层损伤更严重,质量损失率和饱和吸水率也均大于水冻;冻融试块的饱和吸水率曲线呈现出先水平、再下降、后回升的变化趋势;高强混凝土表层氯离子浓度和氯离子扩散系数均随着冻融次数而增加,分别与冻融次数的0.5次方和1次方呈线性关系,同时还受到冻融介质的影响;随着冻融次数的增加,盐冻时混凝土表面氯离子浓度和氯离子扩散系数的增长相比水冻分别快1.1倍和1.69倍。 相似文献
8.
Analysis of the formation conditions and characteristics of interphase and random vanadium precipitation in a low-carbon steel during isothermal heat treatment 下载免费PDF全文
Sayed Ghafar Hashemi B. Eghbali 《矿物冶金与材料学报》2018,25(3):339-349
The characteristics of nanosized precipitates in steels depend on the heat-treatment parameters. The effects of characteristics of vanadium precipitates formed during isothermal heat treatment on the hardness of the ferrite matrix in low-carbon vanadium-alloyed steel were investigated through analysis of transmission electron microscopy images and microhardness measurements. The results show that, during isothermal holding in the temperature range from 675 to 750℃, only interphase precipitation occurs, whereas only random precipitation occurs in the ferrite matrix during holding at 600℃. Furthermore, during isothermal heat treatment between 600 and 675℃, both random and interphase precipitates occurred in the ferrite. Nanoscale vanadium carbides with different atomic ratios of vanadium (V) and carbon (C) were the dominant precipitates in the random and interphase precipitates. The sizes of random precipitation carbides were smaller than those of interphase ones. Also, the sample isothermally heat treated at 650℃ for 900 s exhibited a higher hardness with a narrower hardness distribution. 相似文献
9.
东北三省资金使用效率研究对于评价振兴东北老工业基地战略具有重要意义.选取东北三省46家上市公司作为研究对象,运用数据包络模型(DEA)中的BCC模式对6个行业的货币资金总体使用效率、纯技术效率和规模效率分别进行分析,并进一步对无效率企业进行投影分析.研究结果显示,制造业资金使用效率较低,其中有较多企业存在投入冗余和产出不足;电力、热力、燃气及水生产和供应业以及信息技术行业资金使用效率较高;批发零售业、交通运输业和房地产业资金使用效率有很大提升空间.最后根据分析结果,提出了改善资金管理方式、加强技术创新、资金投入规模应与企业规模相当等对策建议. 相似文献
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