Dielectric relaxation and conduction mechanism in Aurivillius ceramic Bi5Ti3FeO15

For this study, we synthesized Aurivillius Bi5Ti3FeO15 ceramic using the generic solid-state reaction route and then performed room-temperature X-ray diffraction to confirm that the compound had a single phase with no impurities. The surface morphology of the prepared sample was observed to contain microstructural grains approximately 0.2–2 μm in size. The dielectric properties of the sample were determ-ined as a function of frequency in a range of approximately 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). Nyquist plots of the impedance data were found to exhibit a semi-circular arc in the high-temperature region, which is explained by the equivalent electrical circuit (R1C1)(R2QC2), where R1 and R2 represent the resistances associated with the grains and grain boundaries, respectively, C1 and C2 are the re-spective capacitances, and Q is the constant phase element (CPE), which accounts for non-Debye type of behavior. Our results indicate that both the resistance and capacitance of the grain boundaries are more prominent than those of the grains. The alternating current (ac) conductiv-ity data were analyzed based on the Jonscher universal power law, which indicated that the conduction process is dominated by the hopping mechanism. The calculated activation energies of the relaxation and conduction processes were very similar (0.32 to 0.53 eV), from which we conclude that the same type of charge carriers are involved in both processes.     

Effect of Co substitution on the structural,dielectric and optical properties of KBiFe2O5

Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample.     

Corrosion behavior of cold-rolled and post heat-treated 316L stainless steel in 0.9wt%NaCl solution

The effect of cold rolling and post-rolling heat treatment on the microstructural and electrochemical properties of the 316L stainless steel was investigated.Two-pass and four-pass cold-rolled stainless steel specimens were heat-treated by annealing at 900℃followed by quenching in water.During the cold rolling,the microstructure of the as-received specimen transformed from austenite to strain-inducedα′-martensite due to significant plastic deformation that also resulted in significant grain elongation(i.e.,~33%and 223%increases in the grain elongation after two and four rolling passes,respectively).The hardness of the heat-treated as-received specimen decreased from HV 190 to 146 due to the recovery and recrystallization of the austenite grain structure.The cyclic polarization scans of the as-rolled and heat-treated specimens were obtained in 0.9wt%NaCl solution.The pitting potential of the four-pass rolled specimen was significantly increased from 322.3 to 930.5 mV after post-rolling heat treatment.The beneficial effect of the heat treatment process was evident from~10-times-lower corrosion current density and two-orders-of-magnitude-lower passive current density of the heat-treated specimens compared with those of the as-rolled specimens.Similarly,appreciably lower corrosion rate(3.302×10^?4mm/a)and higher pitting resistance(1115.5 mV)were exhibited by the postrolled heat-treated specimens compared with the as-rolled 316L stainless steel specimens.     

基于负温度系数热敏电阻多通道高精度可穿戴式体温采集系统的设计

体温通常用于筛查传染病、监测治疗.为了确定皮肤表面温度.通过恒压式测温电路测电阻的方法,研究设计了可穿戴式多点体温监测系统,以STM32F103C8T6芯片为核心处理器,负温度系数热敏电阻(negative temperature coefficient,NTC)作为感温元器件,ADS1256芯片为温度信号调理器,蓝牙模块为无线传输单元,用LABVIEW设计上位机界面.热敏电阻及分压电阻构成的恒压式电桥电路进行8路温度数据的采集,24bits超高精度模数转换模块配置差分输入对模拟信号进行放大、滤波以及模数转换;转换后的数据在单片机中处理和运算;最终通过蓝牙将数据传至上位机.采用Stein-hart方程的四阶公式对热敏电阻作线性补偿.从软件和硬件上减少环境干扰和体温分布不均的影响.分析了温传感器的温度测量误差.实验结果表明,测量系统分辨率达0.01℃,测温准确度可达±0.02℃.此设计方案,具有较高的稳定性和精确性;并且该电路结构简单、体积小、低功耗,可用于需要精密测体温场合.     

海上电泵结蜡井热循环洗井工艺参数优化设计

为探索海上油田电泵举升结蜡井热循环洗井工艺井筒温度场分布规律，综合考虑潜油电机增温、电缆散热、热流体注入量、注入深度、注入温度、结蜡管段传热和海水空气导热的影响，基于热能守恒原理，建立了电泵井结蜡热循环洗井工艺井筒温度场计算模型，分析了热流体注入温度和注入量对混合产出流体的井筒温度分布的影响。研究结果表明，随着注入量的增加混合产出液沿程井筒温度增加，随着注入温度的增加混合产出液沿程井筒温度增加。该方法可有效指导现场措施工艺的实施，达到延长结蜡井的清蜡周期、延缓产液/产油量下降速度的目的。     

中国三大产业结构演进规律与发展趋势研究

产业结构对国家经济发展有着重要影响。基于产业结构升级的视角,分5个特征阶段对中国1949～2018年间国内生产总值、三大产业增加值及占比等数据进行了分析,发现新中国成立以来中国产业结构在一系列政策措施的指引下不断优化升级,逐步向产业结构合理发展方向靠拢,形成了"一二三、二一三、二三一、三二一"的演进历程,与产业结构的一般发展规律逐渐契合。在此基础上,解析了中国当前产业政策下产业发展存在的区域发展、产业结构、劳动力分配等主要问题,并为中国产业结构调整升级提出了政策建议。     

面向不平衡数据集融合Canopy和K-means的SMOTE改进算法

针对SMOTE算法和随机森林可较好解决不平衡数据集的分类问题但对少数类样本分类效果还有待提高的问题,融合Canopy和K-means两种聚类算法,设计了C-K-SMOTE改进算法。先后利用Canopy算法进行快速近似聚类,再利用K-means算法进行精准聚类,得到精准聚类簇,最后利用SMOTE算法增加少数类样本数量,使数据趋于平衡。选取公开数据集KEEL(knowledge extraction on evolutionary learning)数据库中的不平衡数据集,结合随机森林分类模型进行了实验验证,实验表明C-K-SMOTE算法可有效平衡不平衡数据集。     

ZIF-67制备的磷掺杂碳催化剂及其氧还原性能

开发高效、廉价的碳基氧还原(ORR)催化剂是质子交换膜燃料电池等先进能源系统商业化应用的关键。以金属有机框架材料ZIF-67为原料,通过热处理、磷掺杂等过程得到高性能的ORR催化剂。该催化剂对ORR具有优异的催化性能,相较于商业Pt/C催化剂,其具有更高中部电位(Half-wave potential)。与此同时,该催化剂还具有非常好的甲醇耐受性与稳定性,并对四电子催化过程具有非常高的选择性。     

妈妈竟然成了我的性幻想对象

<正>金迈的故事我是一个性格内向、安静又善于思考的男生,读书从没让父母操过心。然而,今年夏天发生的一件令人难以启齿的事情,不仅彻底毁灭了我宁静、单纯的小世界,而且让我从此坠入了痛苦的深渊,龌龊、罪恶感像野草般疯长。中考结束后,父母问我想到哪儿玩,我说,哪儿也不去。妈妈是老师,她开玩笑地建议我,适当买两本情感方面的名著,比如《安娜·卡列妮娜》、《乱世佳人》等,免得我读书把自己读呆了,连个媳妇都找不到。我按照妈妈的建议买回了这两本书,坐在书桌前,一个全新的世界渐渐展现在了我的面前。尤其让我惊讶的是,男女之间情感