SrFCl:Eu~(2+)晶体的电子自旋共振谱研究

用程序降温法生长了SrFCl:Eu~(2+)晶体,并测量了它的电子自旋共振谱。应用最小二乘法拟合技术对g因子及自旋哈密顿参数进行了精确拟合。报道了各向异性的g因子及有关自旋哈密顿参量。发现并归属了Eu~(2+)的高阶禁阻跃迁。     

超微粒MnO_2的合成

以MnCl_2和NaOH为原料,采用胶溶法,制备了超微粒MnO_2制得的MnO_2超微粒为非晶态,直径6.0～10.0 nm,呈球状,在有机溶剂中具有良好的分散性和透明性,考察了影响氧化锰溶胶调制的因素,获得了最佳制胶条件,研究了表面活性剂用量与Mn迁移率的关系;通过X-光粉末衍射、红外光谱、热重及差热分析,研究了产品的结构性能。     

ZrO_2纳米微粒红外振动特征

测定了单斜ＺｒＯ_２纳米材料在各种粒度下的付里叶变换红外光声光谱（ＦＴ—ＩＲ—ＰＡＳ），发现随粒度的减小，大部分的谱线位置蓝移，而有些谱线的位置红移，同时在不同频段，有的强度增强，有的强度减弱甚至消失。研究了量子尺寸效应和介电限城效应对其光学特征的影响，对观察到的物理现象进行了物理机制探讨     

苯酚的直接催化羟基化及其产物的气相色谱分析

具有ＭＥＬ拓扑结构的新型钛硅沸石ＴＳ－２，对用Ｈ２Ｏ２直接将苯酚选择性氧化为邻、对苯二酚的反应，表现出优良的催化活性，Ｈ２Ｏ２的选择率和产物所上率都很高。产品混合物的定量分析采用气相色谱法，以ＯＶ－２５为固定液、联苯为内标，得到了令人满意的结果。     

B值随机变量序列部分和的矩的收敛速度

本文讨论2阶一致光滑空间及2型空间中随机变量序列部分和的矩的收敛速度问题,所得定理推广了Chow的结果。     

Resource Search in Unstructured Peer-to-Peer System Based on Multiple-Tree Overlay Structure

We propose a multiple-tree overlay structure for resource discovery in unstructured P2P systems. Peers that have similar interests or hold similar type of resources will be grouped into a tree-like cluster. We exploit the heterogeneity of peers in each cluster by connecting peers with more capacities closer to the root of the tree. The capacity of a peer can be defined in different ways （e.g. higher network bandwidth, larger disk space, more data items of a certain type etc.） according to different needs of users or applications.     

How do Shp2 mutations that oppositely influence its biochemical activity result in syndromes with overlapping symptoms?

Activating and inactivating mutations of SHP-2 are responsible, respectively, for the Noonan (NS) and the LEOPARD (LS) syndromes. Clinically, these developmental disorders overlap greatly, resulting in the apparent paradox of similar diseases caused by mutations that oppositely influence SHP-2 phosphatase activity. While the mechanisms remain unclear, recent functional analysis of SHP-2, along with the identification of other genes involved in NS and in other related syndromes (neurofibromatosis-1, Costello and cardio-facio-cutaneous syndromes), strongly suggest that Ras/MAPK represents the major signaling pathway deregulated by SHP-2 mutants. We discuss the idea that, with the exception of LS mutations that have been shown to exert a dominant negative effect, all disease-causing mutations involved in Ras/MAPK-mediated signaling, including SHP-2, might lead to enhanced MAPK activation. This suggests that a narrow range of MAPK signaling is required for appropriate development. We also discuss the possibility that LS mutations may not simply exhibit dominant negative activity. Received 30 November 2006; received after revision 8 February 2007; accepted 13 March 2007     

纳米固体超强酸SO42-/ZnO催化合成乙酸异戊酯的研究

本文利用纳米固体超强酸SO4^2-/ZnO催化合成乙酸异戊酯的最佳反应条件,既反应时间2.0h,催化剂用量为酸质量的1.0%,酸醇比为1∶2,验证实验产率为96.7%,且该实验反应时间短,无腐蚀无污染,催化剂可回收可重复利用.     

关于2-群的注记

通过对2-群的研究，得到了一类2-群的结构，进而给出了一类无限2-群有无限的阿贝尔子群的例子．     

2,3-二溴甲基-5,6-二氰基吡嗪的合成新方法

以2,3-二甲基-5,6-二氰基吡嗪为原料,在AIBN的引发下,用NBS进行自由基溴化反应,合成了标题产物,其结构经熔点,MS,1HNMR,UV等予以确证,从而为该物质的合成探索了一条新途径.