Timing of the Wudangshan, Yaolinghe volcanic sequences and mafic sills in South Qinling: U-Pb zircon geochronology and tectonic implication

The Wudangshan, Yaolinghe volcanic-sedimentary sequences and doleritic-gabbroic sills comprise the largest exposed Precambrian basement in South Qinling. Zircons separated from 5 volcanic-pyroclastic samples of the Wudangshan Group, 2 volcanic samples of the Yaolinghe Group and one sample for the mafic sills were used for U-Pb dating by laser ablation-inductively coupled plasma mass spectrometry （LA-ICPMS）. The results reveal that the Wudangshan volcanic sequence was formed at （755±3） Ma （a weighted mean from the 5 samples, MSWD=0.47）, whereas the Yaolinghe volcanic suite and the mafic sill were crystallized at （685±5） （2 samples, MSWD=0.36） and （679±3） Ma （MSWD=1.6）, respectively, which are equal to each other within analysis errors. These ages are markedly younger than those previously documented for the rocks. The newly obtained ages for the Wudangshan and Yaolinghe Groups are Identical to those of the bottom Liantuo and slightly older than those of the Nantuo Formations, respectively, lower strata of the Nanhua （middle to late Neoproterozoic） stratotype section in eastern Three Gorges, Yangtze creton. A range of inherited magmatic zircons was recognized with ages of 830 to 780 Ma, which are typical of Neoprotzrozoic magmatisms recorded along the margins and interior of the Yangtze craton. Thus, there is Neoproterozoic basement comprising 830-780 Ma igneous suites in South Qinling; the inherited zircons were detrital sediments derived from the northern margin of the Yangtze craton. Accordingly, it is suggested that the South Qinling is a segment of the Yangtze creton before the Qinling Orogeny.     

Metallogenetic epoch and mechanism of the tungsten ore in Yushan,Beishan orogenic belt,Gansu

Using SHRIMP zircon U-Pb dating methods and cathodoluminescence （CL） technique, we have precisely dated ore samples from tungsten ore deposit, ore-bearing volcanic-sedimentary strata and granite in the Yushan region within the east Tianshan-Beishan W-bearing zone. This study reveals Yushan tungsten ore deposit zone formed in 250 ± 9 Ma, and it is closely associated with the Permian granites and felsic volcanic rocks. This new type of tungsten ore deposit in the east Tianshan-Beishang multiple-metallogenetic province may probably be associated with the regionally right-literal shearing after the main Carboniferous collisional orogeny, and the formation of pull-apart basin and the felsic magmatism.     

黑龙江鹿鸣钼矿床流体包裹体特征

鹿鸣钼矿床位于小兴安岭-张广才岭成矿带中南部.钼矿体产于二长花岗岩与花岗斑岩的接触带内,钼矿化主要载体为石英脉,呈脉状、网脉状分布于矿体的内部.研究了主要含矿石英脉体中流体包裹体的特征,结果表明:包裹体相态类型主要为气液两相,矿床的成矿温度峰值分别为400,220℃,盐度为19%~144%,成矿压力平均为18MPa,成矿深度为09~28km,成矿流体成分富含CO2,H2O,CH4等多种气态组分,以及Na+,Ca2+,SO2-4,Cl-液态组分;矿床初始流体来源于岩浆热液,成矿后期受大气降水的混入.矿床成因类型应划归为与中酸性侵入岩浆活动有关的中高温斑岩型钼矿床.     

大兴安岭柴河流纹质碎斑熔岩锆石U-Pb定年及成因探讨

为了研究大兴安岭柴河地区流纹质碎斑熔岩的形成时代和岩石成因,进行了锆石U-Pb同位素年龄测试和地球化学分析.LA-ICP-MS锆石U-Pb定年结果显示,柴河流纹质碎斑熔岩形成于年龄为135~138Ma的早白垩世。岩石地球化学研究表明,柴河流纹质碎斑熔岩具有高硅富碱、贫钙镁的特征;稀土丰度总量∑REE介于1501×10-6~1915×10-6,轻重稀土分馏明显,m(La)/m(Yb)N=118~1445,Eu负异常(δEu=059~075);微量元素以富集Rb,Ba,K,亏损Nb,P和Ti为特征,与I型花岗岩相似;碎斑熔岩原始岩浆来源于地壳岩石的部分熔融.     

用同位素稀释法测定牛肝和人血清中的锌和硒

结合阴离子交换树脂分离及巯基棉分离技术,采用同位素稀释-电感耦合等离子体质谱法测量了国际比对样品CCQM-K49牛肝样品和人血清样品中的锌和硒。结果表明,对于待测元素含量较高的样品,不经分离,高倍稀释可有效减少基体的干扰;而对待测元素含量较低的样品,则必须经过分离才能准确测量。CCQM-K49牛肝样品中锌和硒的质量分数分别为(179.8±1.2)×10^-6和(2.067±0.027)×10^-6,BW3215人血清标准物质中锌的质量分数为(1.164±0.024)×10^-6,国际比对IMEP-17人血清样品中硒的质量分数(0.0780±0.0014)×10^-6,测量结果均与比对的中心值接近,符合检测的要求。     

四川盆地西部上三叠统须家河组物质来源：碎屑锆石LA-ICP-MS U-Pb年龄研究

对四川盆地西部晚三叠世须三期须家河组碎屑长石石英砂岩和须四期砂岩中碎屑锆石进行了U-Pb定年。分析研究表明:1川西西部都江堰地区沉积物样品具四个主要年龄峰分别为245 Ma、460 Ma、773 Ma和1 836 Ma;川西北部广元地区样品具四个主要年龄峰分别为245 Ma、452 Ma、834 Ma和1 850 Ma;2结合碎屑锆石U-Pb测年特征,表明川西盆地北段广元地区和中段都江堰地区须家河组上部和下部年代学以及地球化学信息一致,主要显示吕梁期(峰值1 836 Ma、1 950 Ma和1 850 Ma),晋宁末期(峰值为865 Ma和834 Ma),加里东期(峰值为460 Ma和452 Ma)和海西-印支期年龄峰(峰值为245Ma),反映两个地区具有相似物源;3结合碎屑锆石U-Pb年龄与周源造山带对比分析,海西-印支期碎屑物质来源于秦岭造山带;加里东期是秦岭造山带的主要造山阶段,秦岭造山带为该阶段提供物源;晋宁末期是扬子克拉通岩浆活动最活跃时期,扬子克拉通为该阶段碎屑物质主要源区;吕梁期碎屑锆石,主要来自其北缘的华北克拉通。     

Eh和pH值对生物滞留系统DNRA作用的影响研究

试验以模拟生物滞留系统为研究对象,运用15N同位素示踪技术研究土壤不同Eh和pH条件下硝酸盐异化还原为氨(DNRA)作用对氮的去除效果。结果表明：在土壤Eh为225 mV～100 mV、0 mV～-120 mV和-225 mV～-340 mV条件下,随着Eh的降低,DNRA作用增强;生物滞留系统中同时存在反硝化反应和DNRA作用,在0 mV～-120 mV区间,更有利于反硝化作用的发生,在-225 mV～-340 mV区间,更有利于DNRA作用的发生;生物滞留系统土壤pH为5～7的条件下,DNRA作用效果随着pH值的增加而增强,在pH为7～9时,DNRA作用效果随着pH值的增加而减弱,表明DNRA作用易在中性偏碱性的环境下发生。     

Geochemical identification of coal-sourced oils and interbedded shale-sourced oils as revealed by compound specific carbon isotopic analysis

To date, questions remain as to how to differentiate between coaland interbedded shale-sourced oils in coal measures. Based on the hypothesis that δ¹³C value of sedimentary organic matter is controlled by the depositional environment and productivities of biota grown in such depositional setting, this note examines compound specific carbon isotopic profiles from coal and interbedded shale extracts using the gas chromatography-isotope ratio mass spectrometry technique (GC/IRMS). The results show that compound specific carbon isotope values from coal extracts are enriched in¹³C relative to that of interbedded shale extracts, and provide useful information in characterizing coal- and interbedded shale-sourced oils in coal measures. An example for its successful application from the Turpan Basin, Northwestern China is presented.     

Anomalously high δ D and micro-scale hydrogen isotope heterogeneities in the mantle: Ion microprobe analysis of am-iboles from peridotite xenoliths at Nushan, eastern China

Hydrogen isotopic compositions of four amphibole grains from three pieces of lherzolite xenoliths in Cenozoic basanites of Nushan, eastern China have been analyzed by ion microprobe. δ D values of all analyzed points range from ?94‰ to +46‰, some of which are much higher than the highest δ D (+8‰) reported previously for mantle materials. The heterogeneities of D/H ratios within single grains have been observed, the variation of δ D is up to 80‰ on the scale of less than 400 ?m. No correlation between hydrogen isotopic ratios and hydrogen contents can be found, implying that the scatter of δ D values could not result from a late shallow process such as hydrogen loss or hydrothermal alterations and should be considered as inherited from the source at depth. Chemical compositions of Nushan amphiboles are very homogeneous, excluding the fact that the scatter of δ D values could arise from variable fractionation factors between a single fluid source and minerals. Therefore, metasomatic fluids responsible for the formation of Nushan amphiboles should be heterogeneous and result in the observed large variable and anomalously high δ D values of amphiboles. We suggested that such metasomatic fluids could be related to magma degassing in the mantle source. Based on the D-H diffusion data and the scale of hydrogen isotope heterogeneities, it was inferred that the mantle metasomatism took place soon before the eruption of host magma.     

再建气候环境演化历史的碳同位素技术

稳定碳同位素是再建气候环境变化历史最重要手段。简要回顾了碳同位素分馏的主要影响因素。介绍了碳同位素变化与生态环境变迁的可能关系 ;重点探讨了利用碳同位素再建古大气CO2 的原理和方法