全安盆地水文地质特征及热水成因分析

在简要分析全安盆地水文地质特征、地下水赋存条件及划分地下水类型基础上,对盆地西部周地-暖水塘地区地下热水形成原因、赋存环境进行研究,认为多期次构造运动形成的断裂、裂隙沟通深部地下热水是盆地热水来源的主要原因;采取地下热水样品并开展氢氧稳定同位素、选出气体、水化学成份测试,认为地下热水由大气降水补给,长期水动态观测结果也显示大气降水与地下热水关系较密切.     

湘江沉积物铅污染计算

湘江是我国重金属污染最严重的河流之一。本次工作利用多接收同位素质谱（MC-ICP-Ms）技术,分析湘江入湖沉积物的Pb同位素组成。结果表明,湘江三角洲沉积物存在严重的pb污染。Pb同位素源区示踪分析表明,河床沉积物的铅为花岗岩自然Pb、Pb-zn矿床的矿石铅和燃煤烟尘铅的三元混合铅,其中花岗岩占20％,华南煤所占比例为10％,方铅矿所占比例为70％。;湖盆沉积物中的铅则以Pb-Zn矿床的矿石铅和燃煤烟尘铅构成的人为源Pb为主．受上游岩石风化影响较小。     

江西南部版石盆地火山岩SHRIMP锆石U-Pb年龄及其地质意义

应用SHRIMP锆石U-Pb定年方法,对江西南部三南-寻乌火山岩带版石盆地原鸡笼嶂组凝灰岩和原版石组流纹岩开展年代学研究.结果表明,凝灰岩SHRIMP锆石U-Pb年龄为(142.5±1.3)Ma,流纹岩SHRIMP锆石U-Pb年龄为(131.4±1.3)Ma.根据新的国际地层表,晚侏罗世与早白垩世的界线划在(145.5...     

稻叶分段硅同位素组成及硅、钾、钠、钙、镁分布特征

 稳定性硅同位素在植物体内的组成模式对研究硅生物循环、植物硅积累的机理具有重大意义。通过水培试验,研究了成熟期水稻叶内硅同位素组成及Si、K、Na、Ca和Mg营养元素的分布情况。试验结果表明,将水稻叶沿长轴按叶鞘、叶片基段、叶片中段和叶片顶段4部分划分后,各段的Si质量分数和δ³⁰Si值都存在显著差异,并呈现从叶下部到上部逐渐增加的一致趋势。在测定的其它营养元素中,只有Ca在水稻叶中的分布与Si类似,K和Na在叶鞘中的质量分数高于叶片,Mg在叶不同部位质量分数没有显著差异。本试验中水稻叶不同部位δ³⁰Si值变化范围是-0.25%～0.23%,超出了目前已知陆生植物样品δ³⁰Si值的变化范围（-0.17%～0.25%）。试验结果显示了水稻叶内硅分布主要受蒸腾作用的影响,硅同位素在叶中的分馏属于同位素动力学分馏。     

12C与133Cs反应中Ba同位素的Qgg产额依赖

使用47MeV/u12C离子轰击133Cs靶,由多核子转移反应产生Ba同位素。使用放射化学方法,从133Cs和反应产物中分离出产物Ba,再使用高纯Ge探测器测量Ba放射性同位素的γ活性,根据Ba同位素的活度和其他相关数据,确定Ba同位素的产生截面。通过分析测得的Ba同位素的厚靶平均产生截面,发现缺中子Ba同位素的独立截面不遵从规则的Qgg系统性。该结果可用重离子碰撞中的次级过程加以解释。     

In situ simultaneous determination of trace elements, U-Pb and Lu-Hf isotopes in zircon and baddeleyite

This paper describes a combined method of simultaneously measuring U-Pb and Lu-Hf isotopes as well as trace elements in Phalaborwa baddeleyite and 91500, GJ-1, TEMORA-1 and SK10-2 zircons by means of Neptune MC-ICPMS and Agilent Q-ICPMS connected to a 193 nm excimer laser ablation system. Material ablated by laser was carried in different proportions into Q-ICPMS for U-Pb isotopic and trace elemental and MC-ICPMS for Lu-Hf isotopic compositions. Experiments indicate that different proportions of ablated material for the Q-ICPMS and MC-ICPMS （6：4, 5：5 and 4：6 respectively） do not show any bias for the zircon/baddeleyite U-Pb age, Lu-Hf isotope and trace elemental compositions within analytical errors. Using 40-60 μm spot size, the obtained U-Pb ages of Phalaborwa baddeleyite, 91500, GJ-1, TEMORA and SK10-2 zircons are 2065±15 （2σ, n=20）, 1063±6 （2σ, n=-19）, 613±6 （2σ, n=20）, 416±5 （2σ, n=20） and 32.6±0.5 （2σ, n=20） Ma, respectively. The ^176Hf/^177Hf ratios are 0.281231±24 （2SD, n=20）, 0.282310±35 （2SD, n=19）, 0.282028±34 （2SD, n=20）, 0.282687±34 （2SD, n=20） and 0.282752±53 （2SD, n=20）, respectively. The obtained trace elemental compositions are identical to the reference values. Therefore, this kind of technique makes it possible to simultaneously obtain the U-Pb age, Lu-Hf isotopes and trace elemental compositions of zircon and baddeleyite, which could be an important tool in solving problems in earth sciences.     

Asian summer monsoon precipitation recorded by stalagmite oxygen isotopic composition in the western Loess Plateau during AD1875―2003 and its linkage with ocean-atmosphere system

Based on 5 high-precision ^230Th dates and 103 stable oxygen isotope ratios （51eO） obtained from the top 16 mm of a stalagmite collected from Wanxiang Cave, Wudu, Gansu, variation of monsoonal precipitation in the modern Asian Monsoon （AM） marginal zone over the past 100 years was reconstructed. Comparison of the speleothem δ^18O record with instrumental precipitation data at Wudu in the past 50 years indicates a high parallelism between the two curves, suggesting that the speleothem δ^18O is a good proxy for the AM strength and associated precipitation, controlled by ＂amount effect＂ of the precipitation. Variation of the monsoonal precipitation during the past 100 years can be divided into three stages, increasing from AD 1875 to 1900, then decreasing from AD 1901 to 1946, and increasing again thereafter. This variation is quite similar to that of the Drought/Flooding index archived from Chinese historical documents. This speleothem-derived AM record shows a close association with the Pacific Decadal Oscillation （PDO） between AD 1875 and 1977, with higher monsoonal precipitation corresponding to cold PDO phase and vice versa at decadal timescale. The monsoonal precipitation variation is out of phase with the PDO after AD 1977, probably resulting from the decadal climate jump in the north Pacific occurring at around AD 1976/77. These results demonstrate a strong linkage between the AM and associated precipitation and the Pacific Ocean via ocean/atmosphere interaction. This relationship will aid to forecast future hydrological cycle for the AM monsoon region, and to improve forecasting potential of climatic model with observation data from cave.     

Caledonian reworking of Paleoproterozoic basement in the Cathaysia Block: Constraints from zircon U-Pb dating,Hf isotopes and trace elements

A combined study of zircon U-Pb dating, Hf isotopes and trace elements has been carried out for granodioritic neosomes of migmatites from the Tianjingping area in northwestern Fujian Province. Zircons are characterized by zoning, higher Th/U ratios （mostly≥0.1）, HREE enrichment, and positive Ce and negative Eu anomalies, and show features similar to magmatic or anatectic zircons. Apparent ^206Pb/^238U ages for the zircons are 447±2 Ma （95 % conf., MSWD=0.88）, corresponding to a Caledonian event. εHf（t） values are -13.3 to -9.7, indicating a crustal source. Two-stage Hf model ages are 1.7 to 1.9 Ga, suggesting that protolith of the migmates was probably formed in the Paleoproterozoic. The granodioritic neosomes have the characteristics of peraluminous calc-alkaline granite, and their REE patterns and trace elements spidergrams show features of middle to upper crustal rocks. Together with previous studies, we conclude that the protolith of the Cathaysia basement in the Tianjingping area was likely formed in the middle-late Paleoproterozoic and experienced partial melting during the Caledonian period. The recognition of Caledonian reworking of the Paleoproterozoic basement in the Cathaysia Block provides a new insight into the tectonic evolution of the Cathaysia Block in the Caledonian period and the interaction between the Cathaysia Block and the Yangtze Block.     

Mesoproterozoic age for Xiamaling Formation in North China Plate indicated by zircon SHRIMP dating

Zircon grains of magmatic origin from tuffite layers in the Xiamaling Formation at Zhaojiashan Village, Xuanhua area, Hebei Province, were used for zircon dating with a Sensitive High-Resolution Ion Microprobe （SHRIMP Ⅱ）, which gives a weighted mean ^207Pb/^206Pb age of 1366±9 Ma. It shows a very similar age （1368±12 Ma） as the zircon dating from the Xiamaling Formation in Western Hill, Beijing. This age proposes that the Xiamaling Formation in the North China plate should be of Mesoproterozoic, instead of Neoproterozoic based on K-Ar, Ar-Ar dating. The new zircon age also indicates the development of macrofossils algae from the Mesoproterozoic age.     

Permian volcanisms in eastern and southeastern margins of the Jiamusi Massif, northeastern China: zircon U-Pb chronology, geochemistry and its tectonic implications

LA-ICP-MS zircon U-Pb dating and geochemical data for the Late Paleozoic volcanic rocks from eastern and southeastern margins of the Jiamusi Massif are presented to understand the regional tectonic evolution. Zircons from eight representative volcanic rocks are euhedral-subhedral in shape and display striped absorption and fine-scale oscillatory growth zoning as well as high Th/U ratios （0.33-2.37）, implying a magmatic origin. The dating results show that the Late Paleozoic volcanic rocks in the study area can be divided into two stages, i.e., the Early Permian （a weighted mean 205^Pb/238^U age of 288 Ma） and the Middle Permian volcanisms （a weighted mean 205^Pb/238^U age of 268 Ma）. The former is composed mainly of basalt, basaltic-andesite, andesite and minor dacite. They are characterized by low SiO2 contents, high Mg^# （0.40-0.59）, enrichment in Na （Na2O/K2O = 1.26-4.25） and light rare earth elements （LREEs）, relative depletion in heavy rare earth elements （HREEs） and high field strength elements （HFSEs）, indicating that an active continental margin setting could exist in the eastern margin of the Jiamusi Massif in the Early Permian. The latter consists mainly of rhyolite and minor dacite with high SiO2 （77.23%-77.52%）, low MgO （0.11%-0.14%）, enrichment in 1（20 （Na2O/K2O ratios 〈 0.80） and Rb, Th, U and depletion in Eu, Sr, P and Ti, implying a crust-derived origin. Therefore, it is proposed that the Middle Permian volcanic rocks could have formed under the collision of the Jiamusi and the Khanka Massifs.