沉积在氧化铝模板上的纳米SiC的结构和发光性质研究

用二次阳极氧化法制备了高质量的氧化铝模板,用磁控溅射法在氧化铝模板上溅射生长了非晶SiC材料.原子力显微镜结果显示,在不同的溅射气压下(0.5～1.5Pa),能够形成层状、点状和棒状的SiC纳米结构.光致发光谱显示,在550～700nm之间有一个很强的发光峰,随着生长条件的改变,这个发光峰的强度有显著的变化.分析了纳米结构的形成、发光峰的变化与制备条件的关系.     

新型功能化介孔材料CH3-MCM-41-NH2的合成和表征

以硅酸钠为硅源,十六烷基三甲基溴化铵（CTAB）为模板剂,合成介孔材料MCM-41．采用两步嫁接法,分别用三甲基氯化硅（TMSCL）和3-氨基三乙氧基硅烷（APTS）对合成的介孔分子筛进行化学修饰,首次将甲基和氨基同时嫁接到介孔材料MCM-41上,得到新型的介孔材料CH3-MCM-41-NH2．利用XRD和FT—IR对合成的新型功能化介孔材料进行表征．     

First-principles study of the interactions of hydrogen with low-index surfaces of PdCu ordered alloy

PdCu catalysts play a key role in several hydrogen-involved processes. Among these reactions, the interaction of hydrogen with PdCu essentially determines the catalytic performance. However, the response of PdCu to surrounding hydrogen has been poorly investigated, especially for specific facets of PdCu at different environment. In this work, taking temperature and hydrogen pressure into account, we studied the hydrogen-surface interactions for four low-index surfaces of PdCu through first-principles calculations. It was found that H-PdCu adsorption strong relies on the facets, hydrogen coverage, and reaction environment (temperature and H-pressure). Our work highlights the importance of the environment on the nature of catalyst surfaces and reactions and offers a plausible way to investigate the interactions between gas and the surfaces of nanocatalysts in real reactions.     

Fe-Si复合氧化物中孔分子筛的合成与表征

在碱性条件下，采用乙二胺为介质，以十六烷基三甲基溴化胺为模板剂，正硅酸乙酯为硅源，用水热法合成了Fe-Si复合氧化物中孔分子筛，并用XRD、红外、热分析等对样品进行表征，实验结果证实所合成的产物为Fe-Si复合氧化物中孔分子筛。     

掺杂稀土元素对改善氧化铝热稳定性机理的探讨

从阻抑氧化铝的相变、表面化合物的生成和延缓氧化铝的烧结三个方面探讨了氧化铝掺杂镧后改善热稳定性的机理。     

Y/SBA-15的微波水热法合成及其表征分析

研究了微波水热法合成微孔-介孔复合分子筛Y/SBA-15,以XRD为表征手段,考察了pH、二氧化硅与P123物质的量比、微波功率、搅拌速度和晶化温度等因素对复合分子筛结构的影响.经过研究确定了复合分子筛的合成条件:pH值为2.5,SiO2和P123物质的量比为58,微波功率为200W,搅拌速度为250r/min,晶化温度为120℃.采用氮气吸附脱附、透射电镜等分析方法对复合分子筛进行了表征分析,结果表明:合成产物同时具有微孔介孔结构特征,结晶度良好、短棒状大小均匀,微孔、介孔2种孔径分布均匀,平均孔径为4.050 13nm,孔壁厚度为2.2nm,BET孔容为0.350 525cm3/g.     

Extraction and characterization of alumina nanopowders from aluminum dross by acid dissolution process

A significant amount of aluminum dross is available as a waste in foundry industries in Bangladesh. In this study, alumina was extracted from aluminum dross collected from two foundry industries situated in Dhamrai and Manikgang, near the capital city, Dhaka. Aluminum dross samples were found to approximately contain 75wt% Al₂O₃ and 12wt% SiO₂. An acid dissolution process was used to recover the alumina value from the dross. The effects of various parameters, e.g., temperature, acid concentration, and leaching time, on the extraction of alumina were studied to optimize the dissolution process. First, Al(OH)₃ was produced in the form of a gel. Calcination of the Al(OH)₃ gel at 1000℃, 1200℃, and 1400℃ for 2 h produced θ-Al₂O₃, (α+θ)-Al₂O₃, and α-alumina powder, respectively. Thermal characterization of the Al(OH)₃ gel was performed by thermogravimetric/differential thermal analysis (TG/DTA) and differential scanning calorimetry (DSC). The phases and crystallite size of the alumina were determined by X-ray diffraction analysis. The dimensions of the alumina were found to be on the nano level. The chemical compositions of the aluminum dross and alumina were determined by X-ray fluorescence (XRF) spectroscopy. The microstructure and morphology of the alumina were studied with scanning electron microscopy. The purity of the alumina extracted in this study was found to be 99.0%. Thus, it is expected that the obtained alumina powders can be potentially utilized as biomaterials.     

具有LOTS因子的积空间的正交紧性

本文证明当x是点有限仿紧空间时,x与一个核为K的线性序拓扑空间的乘积是正交紧的充要条件是x的正交口径为K,该结果推广了文[1]的一个主要结果,在此基础上,我们给出了点有限仿紧空间与局部紧线性序拓扑空间乘积正交紧性的一个刻划。     

Al2O3陶瓷凝胶注模成型工艺的研究

凝胶注模成型是一种原位成型工艺 ,该工艺是制备形状复杂、成分均匀和可靠性高的陶瓷材料的理想成型工艺。以降低Al2 O3陶瓷浆料的黏度和提高固相含量为重点 ,分别研究了pH值、分散剂、固相含量对浆料黏度的影响 ,以及固相含量对坯体抗弯强度的影响 ,并制备出固相含量 5 5 %、黏度 0 .69Pa·s的Al2 O3浆料 ,其坯体抗弯强度 3 1MPa .     

关于BR0-代数弱完备性的证明

目的对BR0-代数自身的完备性问题进行研究。方法研究了王国俊教授建立的模糊命题演算的形式演绎系统L*和与之在语义上相匹配的R0-代数,并结合吴洪博教授所定义的BR0-代数,从伴随的角度切入。结果在BR0-代数中定义了BR0-等式和BR0-方程,通过全序BR0-代数证明了BR0-代数自身的弱完备性。结论得到了BR0-代数的完备性定理,为相应形式逻辑系统与模糊推理的研究提供了理论框架。